2.5. Gases under pressure
2.5. Gases under pressure
2.5.1.1.
►M4
Gases under pressure are gases which are contained in a receptacle at a pressure of 200 kPa (gauge) or more at 20 °C, or which are liquefied or liquefied and refrigerated. ◄
2.5.1.1. ►M4 Gases under pressure are gases which are contained in a receptacle at a pressure of 200 kPa (gauge) or more at 20 °C, or which are liquefied or liquefied and refrigerated. ◄
They comprise compressed gases, liquefied gases, dissolved gases and refrigerated liquefied gases.
2.5.1.2. The critical temperature is the temperature above which a pure gas cannot be liquefied, regardless of the degree of compression.
2.5.2.
Classification criteria
2.5.2.1. Gases under pressure shall be classified, according to their physical state when packaged, in one of four groups in accordance with Table 2.5.1:
2.5.2.1. Gases under pressure shall be classified, according to their physical state when packaged, in one of four groups in accordance with Table 2.5.1:
Table 2.5.1
Criteria for gases under pressure
|
Group |
Criteria |
|
Compressed gas |
A gas which when packaged under pressure is entirely gaseous at – 50 °C; including all gases with a critical temperature ≤ – 50 °C. |
|
Liquefied gas |
A gas which, when packaged under pressure, is partially liquid at temperatures above – 50 °C. A distinction is made between: (i) high pressure liquefied gas: a gas with a critical temperature between – 50 °C and + 65 °C; and (ii) low pressure liquefied gas: a gas with a critical temperature above + 65 °C. |
|
Refrigerated liquefied gas |
A gas which when packaged is made partially liquid because of its low temperature. |
|
Dissolved gas |
A gas which when packaged under pressure is dissolved in a liquid phase solvent. |
|
Note: Aerosols shall not be classified as gases under pressure. See section 2.3. |
|
2.5.3. Hazard Communication
Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 2.5.2.
Table 2.5.2
Label elements for gases under pressure
|
Classification |
Compressed gas |
Liquefied gas |
Refrigerated liquefied gas |
Dissolved gas |
|
GHS Pictograms |
|
|
|
|
|
Signal Word |
Warning |
Warning |
Warning |
Warning |
|
Hazard Statement |
H280: Contains gas under pressure; may explode if heated |
H280: Contains gas under pressure; may explode if heated |
H281: Contains refrigerated gas; may cause cryogenic burns or injury |
H280: Contains gas under pressure; may explode if heated |
|
Precautionary Statement Prevention |
|
|
P282 |
|
|
Precautionary Statement Response |
|
|
P336 + P315 |
|
|
Precautionary Statement Storage |
P410 + P403 |
P410 + P403 |
P403 |
P410 + P403 |
|
Precautionary Statement Disposal |
|
|
|
|
Note:
Pictogram GHS04 is not required for gases under pressure where pictogram GHS02 or pictogram GHS06 appears.
2.5.4. Additional Classification Considerations
For this group of gases, the following information is required to be known:
Data can be found in the literature, calculated or determined by testing. Most pure gases are already classified in the UN RTDG, Model Regulations.