CELEX 02008R1272 · v20250901

2.5. Gases under pressure

2.5.   Gases under pressure

2.5.1.1.  ►M4  Gases under pressure are gases which are contained in a receptacle at a pressure of 200 kPa (gauge) or more at 20 °C, or which are liquefied or liquefied and refrigerated. ◄

They comprise compressed gases, liquefied gases, dissolved gases and refrigerated liquefied gases.

2.5.1.2. The critical temperature is the temperature above which a pure gas cannot be liquefied, regardless of the degree of compression.

▼M4

2.5.2.    Classification criteria

2.5.2.1. Gases under pressure shall be classified, according to their physical state when packaged, in one of four groups in accordance with Table 2.5.1:

Table 2.5.1

Criteria for gases under pressure

Group

Criteria

Compressed gas

A gas which when packaged under pressure is entirely gaseous at – 50 °C; including all gases with a critical temperature ≤ – 50 °C.

Liquefied gas

A gas which, when packaged under pressure, is partially liquid at temperatures above – 50 °C. A distinction is made between:

(i)  high pressure liquefied gas: a gas with a critical temperature between – 50 °C and + 65 °C; and

(ii)  low pressure liquefied gas: a gas with a critical temperature above + 65 °C.

Refrigerated liquefied gas

A gas which when packaged is made partially liquid because of its low temperature.

Dissolved gas

A gas which when packaged under pressure is dissolved in a liquid phase solvent.

Note:

Aerosols shall not be classified as gases under pressure. See section 2.3.

▼B

2.5.3.   Hazard Communication

Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 2.5.2.

▼M12

Table 2.5.2

Label elements for gases under pressure

Classification

Compressed gas

Liquefied gas

Refrigerated liquefied gas

Dissolved gas

GHS Pictograms

image

image

image

image

Signal Word

Warning

Warning

Warning

Warning

Hazard Statement

H280: Contains gas under pressure; may explode if heated

H280: Contains gas under pressure; may explode if heated

H281: Contains refrigerated gas; may cause cryogenic burns or injury

H280: Contains gas under pressure; may explode if heated

Precautionary Statement Prevention

 

 

P282

 

Precautionary Statement Response

 

 

P336 + P315

 

Precautionary Statement Storage

P410 + P403

P410 + P403

P403

P410 + P403

Precautionary Statement Disposal

 

 

 

 

▼M2

Note:

Pictogram GHS04 is not required for gases under pressure where pictogram GHS02 or pictogram GHS06 appears.

▼B

2.5.4.   Additional Classification Considerations

For this group of gases, the following information is required to be known:

— 
the vapour pressure at 50 oC;
— 
the physical state at 20 oC at standard ambient pressure;
— 
the critical temperature.

▼M4

Data can be found in the literature, calculated or determined by testing. Most pure gases are already classified in the UN RTDG, Model Regulations.

▼B

Source: Content sourced from EUR-Lex and licensed under CC BY 4.0. This is an unofficial presentation; only the official EUR-Lex version is legally authentic.

Screen documents for chemicals