Part 1 / Criteria for the selection of precautionary statements

Part 1: Criteria for the selection of precautionary statements

Table 6.1

Precautionary statements — General

Code

General precautionary statements

Hazard class

Hazard category

Conditions for use

(1)

(2)

(3)

(4)

(5)

P101

If medical advice is needed, have product container or label at hand.

as appropriate

 

Consumer products

P102

Keep out of reach of children.

as appropriate

 

Consumer products

▼M19

P103

Read carefully and follow all instructions.

as appropriate

 

Consumer products – omit where P202 is used

▼B

Code

General precautionary statements

Hazard class

Hazard category

Conditions for use

Code

Code

General precautionary statements

General precautionary statements

Hazard class

Hazard class

Hazard category

Hazard category

Conditions for use

Conditions for use

(1)

(2)

(3)

(4)

(5)

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

(5)

(5)

P101

If medical advice is needed, have product container or label at hand.

as appropriate

 

Consumer products

P101

P101

If medical advice is needed, have product container or label at hand.

If medical advice is needed, have product container or label at hand.

as appropriate

as appropriate

 

 

Consumer products

Consumer products

P102

Keep out of reach of children.

as appropriate

 

Consumer products

P102

P102

Keep out of reach of children.

Keep out of reach of children.

as appropriate

as appropriate

 

 

Consumer products

Consumer products

▼M19

▼M19

▼M19 ▼M19

P103

Read carefully and follow all instructions.

as appropriate

 

Consumer products – omit where P202 is used

P103

P103

Read carefully and follow all instructions.

Read carefully and follow all instructions.

as appropriate

as appropriate

 

 

Consumer products – omit where P202 is used

Consumer products – omit where P202 is used omit where P202 is used

▼B

▼B

▼B ▼B

Table 6.2

Precautionary statements — Prevention

Code

Prevention precautionary statements

Hazard class

Hazard category

Conditions for use

(1)

(2)

(3)

(4)

(5)

▼M19

P201

Obtain special instructions before use.

Explosives (section 2.1)

Unstable explosive

 

Germ cell mutagenicity (section 3.5)

1A,1B, 2

Consumer products – omit where P202 is used

Carcinogenicity (section 3.6)

1A,1B, 2

Reproductive toxicity (section 3.7)

1A,1B, 2

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

P202

Do not handle until all safety precautions have been read and understood.

Flammable gases (section 2.2)

A, B (chemically unstable gases)

 

Germ cell mutagenicity (section 3.5)

1A,1B, 2

 

Carcinogenicity (section 3.6)

1A,1B, 2

 

Reproductive toxicity (section 3.7)

1A,1B, 2

 

Reproductive toxicity, effects on or via lactation (section 3.7)

Additional category

 

P210

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Explosives (section 2.1)

Divisions 1.1, 1.2, 1.3, 1.4, 1.5

 

Flammable gases (section 2.2)

1A, 1B, 2

 

Aerosols (section 2.3)

1, 2, 3

Flammable liquids (section 2.6)

1, 2, 3

Flammable solids (section 2.7)

1, 2

Self-reactive substances and mixtures (section 2.8)

Types A, B, C, D, E, F

Pyrophoric liquids (section 2.9)

1

Pyrophoric solids (section 2.10)

1

Oxidising liquids (section 2.13)

1, 2, 3

 

Oxidising solids (section 2.14)

1, 2, 3

 

Organic peroxides (section 2.15)

Types A, B, C, D, E, F

 

Desensitised explosives (section 2.17)

1, 2, 3, 4

 

▼M4

P211

Do not spray on an open flame or other ignition source.

Aerosols (section 2.3)

1, 2

 

▼M19

P212

Avoid heating under confinement or reduction of the desensitising agent.

Desensitised explosives (section 2.17)

1, 2, 3, 4

 

▼M12

P220

Keep away from clothing and other combustible materials.

Oxidising gases (Section 2.4)

1

 

Oxidising liquids (Section 2.13)

1, 2, 3

Oxidising solids (Section 2.14)

1, 2, 3

▼M12 —————

▼M19

P222

Do not allow contact with air.

Flammable gases (section 2.2)

Pyrophoric gas

Pyrophoric liquids (section 2.9)

1

Pyrophoric solids (section 2.10)

1

▼M12

P223

Do not allow contact with water.

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2

—  if emphasis of the hazard statement is deemed necessary

▼M19

P230

Keep wetted with …

Explosives (section 2.1)

Divisions 1.1, 1.2, 1.3, 1.5

Manufacturer/supplier to specify appropriate material

Desensitised explosives (section 2.17)

1, 2, 3, 4

Manufacturer/supplier to specify appropriate material

▼M12

P231

Handle and store contents under inert gas/…

Pyrophoric liquids (Section 2.9)

1

… Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate.

Pyrophoric solids (Section 2.10)

1

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2, 3

—  if the substance or mixture reacts readily with moisture in air.

… Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate.

▼B

P232

Protect from moisture.

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

 

▼M19

P233

Keep container tightly closed.

Flammable liquids (section 2.6)

1, 2, 3

Pyrophoric liquids (section 2.9)

1

 

Pyrophoric solids (section 2.10)

1

 

Desensitised explosives (section 2.17)

1, 2, 3, 4

 

Acute toxicity – inhalation (section 3.1)

1, 2, 3

Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity – single exposure; narcotic effects (section 3.8)

3

▼M12

P234

Keep only in original packaging.

Explosives (Section 2.1)

Divisions 1.1, 1.2, 1.3, 1.4, 1.5

 

Self-reactive substances and mixtures (Section 2.8)

Types A, B, C, D, E, F

Organic peroxides (Section 2.15)

Types A, B, C, D, E, F

Corrosive to metals (Section 2.16)

1

P235

Keep cool.

Flammable liquids (Section 2.6)

1, 2, 3

—  for flammable liquids category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere

Self-reactive substances and mixtures (Section 2.8)

Types A, B, C, D, E, F

—  may be omitted if P411 is given on the label

Self-heating substances and mixtures (Section 2.11)

1, 2

—  may be omitted if P413 is given on the label

Organic peroxides (Section 2.15)

Types A, B, C, D, E, F

—  may be omitted if P411 is given on the label

P240

Ground and bond container and receiving equipment.

Explosives (Section 2.1)

Divisions 1.1, 1.2, 1.3, 1.4, 1.5

—  if the explosive is electrostatically sensitive

Flammable liquids (Section 2.6)

1, 2, 3

—  if the liquid is volatile and may generate an explosive atmosphere

Flammable solids (Section 2.7)

1, 2

—  if the solid is electrostatically sensitive

Self-reactive substances and mixtures (Section 2.8)

Types A,B,C, D, E, F

—  if electrostatically sensitive and able to generate an explosive atmosphere

Organic peroxides (Section 2.15)

P241

Use explosion-proof [electrical/ventilating/lighting/…] equipment.

Flammable liquids (Section 2.6)

1, 2, 3

Flammable solids (Section 2.7)

1, 2

P242

Use non-sparking tools.

Flammable liquids (Section 2.6)

1, 2, 3

—  if the liquid is volatile and may generate an explosive atmosphere and if the minimum ignition energy is very low. (This applies to substances and mixtures where the ignition energy is < 0,1 mJ, e.g. carbon disulphide).

P243

Take action to prevent static discharges.

Flammable liquids (Section 2.6)

1, 2, 3

—  if the liquid is volatile and may generate an explosive atmosphere.

▼M4

P244

Keep valves and fittings free from oil and grease.

Oxidising gases (section 2.4)

1

 

▼M12

P250

Do not subject to grinding/shock/friction …

Explosives (Section 2.1)

Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5

—  if the explosive is mechanically sensitive

… Manufacturer/supplier to specify applicable rough handling.

▼M4

P251

Do not pierce or burn, even after use.

Aerosols (section 2.3)

1, 2, 3

 

▼B

P260

Do not breathe dust/fume/gas/mist/vapours/spray.

Acute toxicity — inhalation (section 3.1)

1, 2

Manufacturer/supplier to specify applicable conditions.

Specific target organ toxicity — single exposure (section 3.8)

1, 2

Specific target organ toxicity — repeated exposure (section 3.9)

1, 2

Skin corrosion (section 3.2)

1A, 1B, 1C

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

▼M12

P261

Avoid breathing dust/fume/gas/mist/vapours/spray.

Acute toxicity — inhalation (Section 3.1)

3, 4

—  may be omitted if P260 is given on the label

Manufacturer/supplier to specify applicable conditions.

Respiratory sensitisation (Section 3.4)

1, 1A, 1B

Skin sensitisation (Section 3.4)

1, 1A, 1B

Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)

3

Specific target organ toxicity — single exposure; narcotic effects (Section 3.8)

3

▼B

P262

Do not get in eyes, on skin, or on clothing.

Acute toxicity — dermal (section 3.1)

1, 2

 

▼M12

P263

Avoid contact during pregnancy and while nursing.

Reproductive toxicity — effects on or via lactation (Section 3.7)

Additional category

 

▼B

P264

Wash … thoroughly after handling.

Acute toxicity — oral (section 3.1)

1, 2, 3, 4

Manufacturer/supplier to specify parts of the body to be washed after handling.

Acute toxicity — dermal (section 3.1)

1, 2

Skin corrosion (section 3.2)

1A, 1B, 1C

Skin irritation (section 3.2)

2

Eye irritation (section 3.3)

2

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Specific target organ toxicity — single exposure (section 3.8)

1, 2

Specific target organ toxicity — repeated exposure (section 3.9)

1

P270

Do not eat, drink or smoke when using this product.

Acute toxicity — oral (section 3.1)

1, 2, 3, 4

 

Acute toxicity — dermal (section 3.1)

1, 2

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Specific target organ toxicity — single exposure (section 3.8)

1, 2

Specific target organ toxicity — repeated exposure (section 3.9)

1

P271

Use only outdoors or in a well-ventilated area.

Acute toxicity — inhalation (section 3.1)

1, 2, 3, 4

 

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity — single exposure; narcosis (section 3.8)

3

▼M2

P272

Contaminated work clothing should not be allowed out of the workplace.

Skin sensitisation (section 3.4)

1, 1A, 1B

 

▼B

P273

Avoid release to the environment.

Hazardous to the aquatic environment — acute aquatic hazard (section 4.1)

1

Hazardous to the aquatic environment — ►M2  long-term aquatic hazard (section 4.1) ◄

1, 2, 3, 4

▼M2 —————

▼M19

P280

Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…

Explosives (section 2.1)

Unstable explosive and divisions 1.1, 1.2, 1.3, 1.4, 1.5

Manufacturer/supplier to specify the appropriate type of personal protective equipment.

Flammable gases (section 2.2)

Pyrophoric gas

Flammable liquids (section 2.6)

1, 2, 3

Flammable solids (section 2.7)

1, 2

Self-reactive substances and mixtures (section 2.8)

Types A, B, C, D, E, F

Pyrophoric liquids (section 2.9)

1

Pyrophoric solids (section 2.10)

1

Self-heating substances and mixtures (section 2.11)

1, 2

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

Oxidizing liquids (section 2.13)

1, 2, 3

Oxidizing solids (section 2.14)

1, 2, 3

Organic peroxides (section 2.15)

Types A, B, C, D, E, F

Desensitised explosives (section 2.17)

1, 2, 3, 4

Acute toxicity – dermal (section 3.1)

1, 2, 3, 4

Manufacturer/supplier may further specify type of equipment where appropriate.

Skin corrosion (section 3.2)

1A, 1B, 1C

Manufacturer/supplier may further specify type of equipment where appropriate.

Skin irritation (section 3.2)

2

Manufacturer/supplier may further specify type of equipment where appropriate.

Skin sensitisation (section 3.4)

1, 1A, 1B

Serious eye damage (section 3.3)

1

Manufacturer/supplier may further specify type of equipment where appropriate.

Eye irritation (section 3.3)

2

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

Manufacturer/supplier to specify the appropriate type of personal protective equipment.

Carcinogenicity (section 3.6)

1A, 1B, 2

Reproductive toxicity (section 3.7)

1A, 1B, 2

▼M4 —————

▼M12

P282

Wear cold insulating gloves and either face shield or eye protection.

Gases under pressure (Section 2.5)

Refrigerated liquefied gas

 

P283

Wear fire resistant or flame retardant clothing.

Oxidising liquids (Section 2.13)

1

 

Oxidising solids (Section 2.14)

1

 

P284

[In case of inadequate ventilation] wear respiratory protection.

Acute toxicity — inhalation (Section 3.1)

1, 2

—  text in square brackets may be used if additional information is provided with the chemical at the point of use that explains what type of ventilation would be adequate for safe use.

Manufacturer/supplier to specify equipment.

Respiratory sensitisation (Section 3.4)

1, 1A, 1B

▼M4 —————

▼M12

P231 + P232

Handle and store contents under inert gas/…

Protect from moisture.

Pyrophoric liquids (Section 2.9)

1

… Manufacturer/supplier to specify the appropriate liquid or gas if ‘inert gas’ is not appropriate.

Pyrophoric solids (Section 2.10)

1

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2, 3

—  if the substance or mixture reacts readily with moisture in air.

… Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate.

▼M12 —————

▼B

Code

Prevention precautionary statements

Hazard class

Hazard category

Conditions for use

Code

Code

Prevention precautionary statements

Prevention precautionary statements

Hazard class

Hazard class

Hazard category

Hazard category

Conditions for use

Conditions for use

(1)

(2)

(3)

(4)

(5)

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

(5)

(5)

▼M19

▼M19

▼M19 ▼M19

P201

Obtain special instructions before use.

Explosives (section 2.1)

Unstable explosive

 

P201

P201

Obtain special instructions before use.

Obtain special instructions before use.

Explosives (section 2.1)

Explosives (section 2.1)

Unstable explosive

Unstable explosive

 

 

Germ cell mutagenicity (section 3.5)

1A,1B, 2

Consumer products – omit where P202 is used

Germ cell mutagenicity (section 3.5)

Germ cell mutagenicity (section 3.5)

1A,1B, 2

1A,1B, 2

Consumer products – omit where P202 is used

Consumer products – omit where P202 is used omit where P202 is used

Carcinogenicity (section 3.6)

1A,1B, 2

Carcinogenicity (section 3.6)

Carcinogenicity (section 3.6)

1A,1B, 2

1A,1B, 2

Reproductive toxicity (section 3.7)

1A,1B, 2

Reproductive toxicity (section 3.7)

Reproductive toxicity (section 3.7)

1A,1B, 2

1A,1B, 2

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Reproductive toxicity — effects on or via lactation (section 3.7)

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Additional category

P202

Do not handle until all safety precautions have been read and understood.

Flammable gases (section 2.2)

A, B (chemically unstable gases)

 

P202

P202

Do not handle until all safety precautions have been read and understood.

Do not handle until all safety precautions have been read and understood.

Flammable gases (section 2.2)

Flammable gases (section 2.2)

A, B (chemically unstable gases)

A, B (chemically unstable gases)

 

 

Germ cell mutagenicity (section 3.5)

1A,1B, 2

 

Germ cell mutagenicity (section 3.5)

Germ cell mutagenicity (section 3.5)

1A,1B, 2

1A,1B, 2

 

 

Carcinogenicity (section 3.6)

1A,1B, 2

 

Carcinogenicity (section 3.6)

Carcinogenicity (section 3.6)

1A,1B, 2

1A,1B, 2

 

 

Reproductive toxicity (section 3.7)

1A,1B, 2

 

Reproductive toxicity (section 3.7)

Reproductive toxicity (section 3.7)

1A,1B, 2

1A,1B, 2

 

 

Reproductive toxicity, effects on or via lactation (section 3.7)

Additional category

 

Reproductive toxicity, effects on or via lactation (section 3.7)

Reproductive toxicity, effects on or via lactation (section 3.7)

Additional category

Additional category

 

 

P210

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Explosives (section 2.1)

Divisions 1.1, 1.2, 1.3, 1.4, 1.5

 

P210

P210

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Explosives (section 2.1)

Explosives (section 2.1)

Divisions 1.1, 1.2, 1.3, 1.4, 1.5

Divisions 1.1, 1.2, 1.3, 1.4, 1.5

 

 

Flammable gases (section 2.2)

1A, 1B, 2

 

Flammable gases (section 2.2)

Flammable gases (section 2.2)

1A, 1B, 2

1A, 1B, 2

 

 

Aerosols (section 2.3)

1, 2, 3

Aerosols (section 2.3)

Aerosols (section 2.3)

1, 2, 3

1, 2, 3

Flammable liquids (section 2.6)

1, 2, 3

Flammable liquids (section 2.6)

Flammable liquids (section 2.6)

1, 2, 3

1, 2, 3

Flammable solids (section 2.7)

1, 2

Flammable solids (section 2.7)

Flammable solids (section 2.7)

1, 2

1, 2

Self-reactive substances and mixtures (section 2.8)

Types A, B, C, D, E, F

Self-reactive substances and mixtures (section 2.8)

Self-reactive substances and mixtures (section 2.8)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

Pyrophoric liquids (section 2.9)

1

Pyrophoric liquids (section 2.9)

Pyrophoric liquids (section 2.9)

1

1

Pyrophoric solids (section 2.10)

1

Pyrophoric solids (section 2.10)

Pyrophoric solids (section 2.10)

1

1

Oxidising liquids (section 2.13)

1, 2, 3

 

Oxidising liquids (section 2.13)

Oxidising liquids (section 2.13)

1, 2, 3

1, 2, 3

 

 

Oxidising solids (section 2.14)

1, 2, 3

 

Oxidising solids (section 2.14)

Oxidising solids (section 2.14)

1, 2, 3

1, 2, 3

 

 

Organic peroxides (section 2.15)

Types A, B, C, D, E, F

 

Organic peroxides (section 2.15)

Organic peroxides (section 2.15)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

 

 

Desensitised explosives (section 2.17)

1, 2, 3, 4

 

Desensitised explosives (section 2.17)

Desensitised explosives (section 2.17)

1, 2, 3, 4

1, 2, 3, 4

 

 

▼M4

▼M4

▼M4 ▼M4

P211

Do not spray on an open flame or other ignition source.

Aerosols (section 2.3)

1, 2

 

P211

P211

Do not spray on an open flame or other ignition source.

Do not spray on an open flame or other ignition source.

Aerosols (section 2.3)

Aerosols (section 2.3)

1, 2

1, 2

 

 

▼M19

▼M19

▼M19 ▼M19

P212

Avoid heating under confinement or reduction of the desensitising agent.

Desensitised explosives (section 2.17)

1, 2, 3, 4

 

P212

P212

Avoid heating under confinement or reduction of the desensitising agent.

Avoid heating under confinement or reduction of the desensitising agent.

Desensitised explosives (section 2.17)

Desensitised explosives (section 2.17)

1, 2, 3, 4

1, 2, 3, 4

 

 

▼M12

▼M12

▼M12 ▼M12

P220

Keep away from clothing and other combustible materials.

Oxidising gases (Section 2.4)

1

 

P220

P220

Keep away from clothing and other combustible materials.

Keep away from clothing and other combustible materials.

Oxidising gases (Section 2.4)

Oxidising gases (Section 2.4)

1

1

 

 

Oxidising liquids (Section 2.13)

1, 2, 3

Oxidising liquids (Section 2.13)

Oxidising liquids (Section 2.13)

1, 2, 3

1, 2, 3

Oxidising solids (Section 2.14)

1, 2, 3

Oxidising solids (Section 2.14)

Oxidising solids (Section 2.14)

1, 2, 3

1, 2, 3

▼M12 —————

▼M12 —————

▼M12 ————— ▼M12

▼M19

▼M19

▼M19 ▼M19

P222

Do not allow contact with air.

Flammable gases (section 2.2)

Pyrophoric gas

P222

P222

Do not allow contact with air.

Do not allow contact with air.

Flammable gases (section 2.2)

Flammable gases (section 2.2)

Pyrophoric gas

Pyrophoric gas

— if emphasis of the hazard statement is deemed necessary. if emphasis of the hazard statement is deemed necessary

Pyrophoric liquids (section 2.9)

1

Pyrophoric liquids (section 2.9)

Pyrophoric liquids (section 2.9)

1

1

Pyrophoric solids (section 2.10)

1

Pyrophoric solids (section 2.10)

Pyrophoric solids (section 2.10)

1

1

▼M12

▼M12

▼M12 ▼M12

P223

Do not allow contact with water.

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2

—  if emphasis of the hazard statement is deemed necessary

P223

P223

Do not allow contact with water.

Do not allow contact with water.

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2

1, 2

—  if emphasis of the hazard statement is deemed necessary

—  if emphasis of the hazard statement is deemed necessary

▼M19

▼M19

▼M19 ▼M19

P230

Keep wetted with …

Explosives (section 2.1)

Divisions 1.1, 1.2, 1.3, 1.5

Manufacturer/supplier to specify appropriate material

P230

P230

Keep wetted with …

Keep wetted with …

Explosives (section 2.1)

Explosives (section 2.1)

Divisions 1.1, 1.2, 1.3, 1.5

Divisions 1.1, 1.2, 1.3, 1.5

Manufacturer/supplier to specify appropriate material

Manufacturer/supplier to specify appropriate material

— for substances and mixtures which are wetted, diluted, dissolved or suspended with a phlegmatiser in order to suppress their explosive properties for substances and mixtures which are wetted, diluted, dissolved or suspended with a phlegmatiser in order to suppress their explosive properties

Desensitised explosives (section 2.17)

1, 2, 3, 4

Manufacturer/supplier to specify appropriate material

Desensitised explosives (section 2.17)

Desensitised explosives (section 2.17)

1, 2, 3, 4

1, 2, 3, 4

Manufacturer/supplier to specify appropriate material

Manufacturer/supplier to specify appropriate material

▼M12

▼M12

▼M12 ▼M12

P231

Handle and store contents under inert gas/…

Pyrophoric liquids (Section 2.9)

1

… Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate.

P231

P231

Handle and store contents under inert gas/…

Handle and store contents under inert gas/…

Pyrophoric liquids (Section 2.9)

Pyrophoric liquids (Section 2.9)

1

1

… Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate.

… Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate.

Pyrophoric solids (Section 2.10)

1

Pyrophoric solids (Section 2.10)

Pyrophoric solids (Section 2.10)

1

1

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2, 3

—  if the substance or mixture reacts readily with moisture in air.

… Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate.

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2, 3

1, 2, 3

—  if the substance or mixture reacts readily with moisture in air.

… Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate.

—  if the substance or mixture reacts readily with moisture in air.

… Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate.

▼B

▼B

▼B ▼B

P232

Protect from moisture.

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

 

P232

P232

Protect from moisture.

Protect from moisture.

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

1, 2, 3

 

 

▼M19

▼M19

▼M19 ▼M19

P233

Keep container tightly closed.

Flammable liquids (section 2.6)

1, 2, 3

P233

P233

Keep container tightly closed.

Keep container tightly closed.

Flammable liquids (section 2.6)

Flammable liquids (section 2.6)

1, 2, 3

1, 2, 3

— if the liquid is volatile and may generate an explosive atmosphere

Pyrophoric liquids (section 2.9)

1

 

Pyrophoric liquids (section 2.9)

Pyrophoric liquids (section 2.9)

1

1

 

 

Pyrophoric solids (section 2.10)

1

 

Pyrophoric solids (section 2.10)

Pyrophoric solids (section 2.10)

1

1

 

 

Desensitised explosives (section 2.17)

1, 2, 3, 4

 

Desensitised explosives (section 2.17)

Desensitised explosives (section 2.17)

1, 2, 3, 4

1, 2, 3, 4

 

 

Acute toxicity – inhalation (section 3.1)

1, 2, 3

Acute toxicity – inhalation (section 3.1)

Acute toxicity – inhalation (section 3.1)

1, 2, 3

1, 2, 3

— if the chemical is volatile and may generate a hazardous atmosphere

Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8)

Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8)

3

3

Specific target organ toxicity – single exposure; narcotic effects (section 3.8)

3

Specific target organ toxicity – single exposure; narcotic effects (section 3.8)

Specific target organ toxicity – single exposure; narcotic effects (section 3.8)

3

3

▼M12

▼M12

▼M12 ▼M12

P234

Keep only in original packaging.

Explosives (Section 2.1)

Divisions 1.1, 1.2, 1.3, 1.4, 1.5

 

P234

P234

Keep only in original packaging.

Keep only in original packaging.

Explosives (Section 2.1)

Explosives (Section 2.1)

Divisions 1.1, 1.2, 1.3, 1.4, 1.5

Divisions 1.1, 1.2, 1.3, 1.4, 1.5

 

 

Self-reactive substances and mixtures (Section 2.8)

Types A, B, C, D, E, F

Self-reactive substances and mixtures (Section 2.8)

Self-reactive substances and mixtures (Section 2.8)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

Organic peroxides (Section 2.15)

Types A, B, C, D, E, F

Organic peroxides (Section 2.15)

Organic peroxides (Section 2.15)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

Corrosive to metals (Section 2.16)

1

Corrosive to metals (Section 2.16)

Corrosive to metals (Section 2.16)

1

1

P235

Keep cool.

Flammable liquids (Section 2.6)

1, 2, 3

—  for flammable liquids category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere

P235

P235

Keep cool.

Keep cool.

Flammable liquids (Section 2.6)

Flammable liquids (Section 2.6)

1, 2, 3

1, 2, 3

—  for flammable liquids category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere

—  for flammable liquids category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere

Self-reactive substances and mixtures (Section 2.8)

Types A, B, C, D, E, F

—  may be omitted if P411 is given on the label

Self-reactive substances and mixtures (Section 2.8)

Self-reactive substances and mixtures (Section 2.8)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

—  may be omitted if P411 is given on the label

—  may be omitted if P411 is given on the label

Self-heating substances and mixtures (Section 2.11)

1, 2

—  may be omitted if P413 is given on the label

Self-heating substances and mixtures (Section 2.11)

Self-heating substances and mixtures (Section 2.11)

1, 2

1, 2

—  may be omitted if P413 is given on the label

—  may be omitted if P413 is given on the label

Organic peroxides (Section 2.15)

Types A, B, C, D, E, F

—  may be omitted if P411 is given on the label

Organic peroxides (Section 2.15)

Organic peroxides (Section 2.15)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

—  may be omitted if P411 is given on the label

—  may be omitted if P411 is given on the label

P240

Ground and bond container and receiving equipment.

Explosives (Section 2.1)

Divisions 1.1, 1.2, 1.3, 1.4, 1.5

—  if the explosive is electrostatically sensitive

P240

P240

Ground and bond container and receiving equipment.

Ground and bond container and receiving equipment.

Explosives (Section 2.1)

Explosives (Section 2.1)

Divisions 1.1, 1.2, 1.3, 1.4, 1.5

Divisions 1.1, 1.2, 1.3, 1.4, 1.5

—  if the explosive is electrostatically sensitive

—  if the explosive is electrostatically sensitive

Flammable liquids (Section 2.6)

1, 2, 3

—  if the liquid is volatile and may generate an explosive atmosphere

Flammable liquids (Section 2.6)

Flammable liquids (Section 2.6)

1, 2, 3

1, 2, 3

—  if the liquid is volatile and may generate an explosive atmosphere

—  if the liquid is volatile and may generate an explosive atmosphere

Flammable solids (Section 2.7)

1, 2

—  if the solid is electrostatically sensitive

Flammable solids (Section 2.7)

Flammable solids (Section 2.7)

1, 2

1, 2

—  if the solid is electrostatically sensitive

—  if the solid is electrostatically sensitive

Self-reactive substances and mixtures (Section 2.8)

Types A,B,C, D, E, F

—  if electrostatically sensitive and able to generate an explosive atmosphere

Self-reactive substances and mixtures (Section 2.8)

Self-reactive substances and mixtures (Section 2.8)

Types A,B,C, D, E, F

Types A,B,C, D, E, F

—  if electrostatically sensitive and able to generate an explosive atmosphere

—  if electrostatically sensitive and able to generate an explosive atmosphere

Organic peroxides (Section 2.15)

Organic peroxides (Section 2.15)

Organic peroxides (Section 2.15)

P241

Use explosion-proof [electrical/ventilating/lighting/…] equipment.

Flammable liquids (Section 2.6)

1, 2, 3

P241

P241

Use explosion-proof [electrical/ventilating/lighting/…] equipment.

Use explosion-proof [electrical/ventilating/lighting/…] equipment.

Flammable liquids (Section 2.6)

Flammable liquids (Section 2.6)

1, 2, 3

1, 2, 3

— if the liquid is volatile and may generate an explosive atmosphere.

— text in square brackets may be used to specify specific electrical, ventilating, lighting or other equipment if necessary and as appropriate.

Flammable solids (Section 2.7)

1, 2

Flammable solids (Section 2.7)

Flammable solids (Section 2.7)

1, 2

1, 2

— if dust clouds can occur.

— text in square brackets may be used to specify specific electrical, ventilating, lighting or other equipment if necessary and as appropriate.

P242

Use non-sparking tools.

Flammable liquids (Section 2.6)

1, 2, 3

—  if the liquid is volatile and may generate an explosive atmosphere and if the minimum ignition energy is very low. (This applies to substances and mixtures where the ignition energy is < 0,1 mJ, e.g. carbon disulphide).

P242

P242

Use non-sparking tools.

Use non-sparking tools.

Flammable liquids (Section 2.6)

Flammable liquids (Section 2.6)

1, 2, 3

1, 2, 3

—  if the liquid is volatile and may generate an explosive atmosphere and if the minimum ignition energy is very low. (This applies to substances and mixtures where the ignition energy is < 0,1 mJ, e.g. carbon disulphide).

—  if the liquid is volatile and may generate an explosive atmosphere and if the minimum ignition energy is very low. (This applies to substances and mixtures where the ignition energy is < 0,1 mJ, e.g. carbon disulphide).

P243

Take action to prevent static discharges.

Flammable liquids (Section 2.6)

1, 2, 3

—  if the liquid is volatile and may generate an explosive atmosphere.

P243

P243

Take action to prevent static discharges.

Take action to prevent static discharges.

Flammable liquids (Section 2.6)

Flammable liquids (Section 2.6)

1, 2, 3

1, 2, 3

—  if the liquid is volatile and may generate an explosive atmosphere.

—  if the liquid is volatile and may generate an explosive atmosphere.

▼M4

▼M4

▼M4 ▼M4

P244

Keep valves and fittings free from oil and grease.

Oxidising gases (section 2.4)

1

 

P244

P244

Keep valves and fittings free from oil and grease.

Keep valves and fittings free from oil and grease.

Oxidising gases (section 2.4)

Oxidising gases (section 2.4)

1

1

 

 

▼M12

▼M12

▼M12 ▼M12

P250

Do not subject to grinding/shock/friction …

Explosives (Section 2.1)

Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5

—  if the explosive is mechanically sensitive

… Manufacturer/supplier to specify applicable rough handling.

P250

P250

Do not subject to grinding/shock/friction …

Do not subject to grinding/shock/friction …

Explosives (Section 2.1)

Explosives (Section 2.1)

Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5

Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5

—  if the explosive is mechanically sensitive

… Manufacturer/supplier to specify applicable rough handling.

—  if the explosive is mechanically sensitive

… Manufacturer/supplier to specify applicable rough handling.

▼M4

▼M4

▼M4 ▼M4

P251

Do not pierce or burn, even after use.

Aerosols (section 2.3)

1, 2, 3

 

P251

P251

Do not pierce or burn, even after use.

Do not pierce or burn, even after use.

Aerosols (section 2.3)

Aerosols (section 2.3)

1, 2, 3

1, 2, 3

 

 

▼B

▼B

▼B ▼B

P260

Do not breathe dust/fume/gas/mist/vapours/spray.

Acute toxicity — inhalation (section 3.1)

1, 2

Manufacturer/supplier to specify applicable conditions.

P260

P260

Do not breathe dust/fume/gas/mist/vapours/spray.

Do not breathe dust/fume/gas/mist/vapours/spray.

Acute toxicity — inhalation (section 3.1)

Acute toxicity — inhalation (section 3.1)

1, 2

1, 2

Manufacturer/supplier to specify applicable conditions.

Manufacturer/supplier to specify applicable conditions.

Specific target organ toxicity — single exposure (section 3.8)

1, 2

Specific target organ toxicity — single exposure (section 3.8)

Specific target organ toxicity — single exposure (section 3.8)

1, 2

1, 2

Specific target organ toxicity — repeated exposure (section 3.9)

1, 2

Specific target organ toxicity — repeated exposure (section 3.9)

Specific target organ toxicity — repeated exposure (section 3.9)

1, 2

1, 2

Skin corrosion (section 3.2)

1A, 1B, 1C

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

— Specify do not breathe dusts or mists.

— if inhalable particles of dusts or mists may occur during use.

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Reproductive toxicity — effects on or via lactation (section 3.7)

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Additional category

▼M12

▼M12

▼M12 ▼M12

P261

Avoid breathing dust/fume/gas/mist/vapours/spray.

Acute toxicity — inhalation (Section 3.1)

3, 4

—  may be omitted if P260 is given on the label

Manufacturer/supplier to specify applicable conditions.

P261

P261

Avoid breathing dust/fume/gas/mist/vapours/spray.

Avoid breathing dust/fume/gas/mist/vapours/spray.

Acute toxicity — inhalation (Section 3.1)

Acute toxicity — inhalation (Section 3.1)

3, 4

3, 4

—  may be omitted if P260 is given on the label

Manufacturer/supplier to specify applicable conditions.

—  may be omitted if P260 is given on the label

Manufacturer/supplier to specify applicable conditions.

Respiratory sensitisation (Section 3.4)

1, 1A, 1B

Respiratory sensitisation (Section 3.4)

Respiratory sensitisation (Section 3.4)

1, 1A, 1B

1, 1A, 1B

Skin sensitisation (Section 3.4)

1, 1A, 1B

Skin sensitisation (Section 3.4)

Skin sensitisation (Section 3.4)

1, 1A, 1B

1, 1A, 1B

Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)

3

Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)

Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)

3

3

Specific target organ toxicity — single exposure; narcotic effects (Section 3.8)

3

Specific target organ toxicity — single exposure; narcotic effects (Section 3.8)

Specific target organ toxicity — single exposure; narcotic effects (Section 3.8)

3

3

▼B

▼B

▼B ▼B

P262

Do not get in eyes, on skin, or on clothing.

Acute toxicity — dermal (section 3.1)

1, 2

 

P262

P262

Do not get in eyes, on skin, or on clothing.

Do not get in eyes, on skin, or on clothing.

Acute toxicity — dermal (section 3.1)

Acute toxicity — dermal (section 3.1)

1, 2

1, 2

 

 

▼M12

▼M12

▼M12 ▼M12

P263

Avoid contact during pregnancy and while nursing.

Reproductive toxicity — effects on or via lactation (Section 3.7)

Additional category

 

P263

P263

Avoid contact during pregnancy and while nursing.

Avoid contact during pregnancy and while nursing.

Reproductive toxicity — effects on or via lactation (Section 3.7)

Reproductive toxicity — effects on or via lactation (Section 3.7)

Additional category

Additional category

 

 

▼B

▼B

▼B ▼B

P264

Wash … thoroughly after handling.

Acute toxicity — oral (section 3.1)

1, 2, 3, 4

Manufacturer/supplier to specify parts of the body to be washed after handling.

P264

P264

Wash … thoroughly after handling.

Wash … thoroughly after handling.

Acute toxicity — oral (section 3.1)

Acute toxicity — oral (section 3.1)

1, 2, 3, 4

1, 2, 3, 4

Manufacturer/supplier to specify parts of the body to be washed after handling.

Manufacturer/supplier to specify parts of the body to be washed after handling.

Acute toxicity — dermal (section 3.1)

1, 2

Acute toxicity — dermal (section 3.1)

Acute toxicity — dermal (section 3.1)

1, 2

1, 2

Skin corrosion (section 3.2)

1A, 1B, 1C

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

Skin irritation (section 3.2)

2

Skin irritation (section 3.2)

Skin irritation (section 3.2)

2

2

Eye irritation (section 3.3)

2

Eye irritation (section 3.3)

Eye irritation (section 3.3)

2

2

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Reproductive toxicity — effects on or via lactation (section 3.7)

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Additional category

Specific target organ toxicity — single exposure (section 3.8)

1, 2

Specific target organ toxicity — single exposure (section 3.8)

Specific target organ toxicity — single exposure (section 3.8)

1, 2

1, 2

Specific target organ toxicity — repeated exposure (section 3.9)

1

Specific target organ toxicity — repeated exposure (section 3.9)

Specific target organ toxicity — repeated exposure (section 3.9)

1

1

P270

Do not eat, drink or smoke when using this product.

Acute toxicity — oral (section 3.1)

1, 2, 3, 4

 

P270

P270

Do not eat, drink or smoke when using this product.

Do not eat, drink or smoke when using this product.

Acute toxicity — oral (section 3.1)

Acute toxicity — oral (section 3.1)

1, 2, 3, 4

1, 2, 3, 4

 

 

Acute toxicity — dermal (section 3.1)

1, 2

Acute toxicity — dermal (section 3.1)

Acute toxicity — dermal (section 3.1)

1, 2

1, 2

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Reproductive toxicity — effects on or via lactation (section 3.7)

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Additional category

Specific target organ toxicity — single exposure (section 3.8)

1, 2

Specific target organ toxicity — single exposure (section 3.8)

Specific target organ toxicity — single exposure (section 3.8)

1, 2

1, 2

Specific target organ toxicity — repeated exposure (section 3.9)

1

Specific target organ toxicity — repeated exposure (section 3.9)

Specific target organ toxicity — repeated exposure (section 3.9)

1

1

P271

Use only outdoors or in a well-ventilated area.

Acute toxicity — inhalation (section 3.1)

1, 2, 3, 4

 

P271

P271

Use only outdoors or in a well-ventilated area.

Use only outdoors or in a well-ventilated area.

Acute toxicity — inhalation (section 3.1)

Acute toxicity — inhalation (section 3.1)

1, 2, 3, 4

1, 2, 3, 4

 

 

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

3

3

Specific target organ toxicity — single exposure; narcosis (section 3.8)

3

Specific target organ toxicity — single exposure; narcosis (section 3.8)

Specific target organ toxicity — single exposure; narcosis (section 3.8)

3

3

▼M2

▼M2

▼M2 ▼M2

P272

Contaminated work clothing should not be allowed out of the workplace.

Skin sensitisation (section 3.4)

1, 1A, 1B

 

P272

P272

Contaminated work clothing should not be allowed out of the workplace.

Contaminated work clothing should not be allowed out of the workplace.

Skin sensitisation (section 3.4)

Skin sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

 

 

▼B

▼B

▼B ▼B

P273

Avoid release to the environment.

Hazardous to the aquatic environment — acute aquatic hazard (section 4.1)

1

P273

P273

Avoid release to the environment.

Avoid release to the environment.

Hazardous to the aquatic environment — acute aquatic hazard (section 4.1)

Hazardous to the aquatic environment — acute aquatic hazard (section 4.1)

1

1

— if this is not the intended use.

Hazardous to the aquatic environment — ►M2  long-term aquatic hazard (section 4.1) ◄

1, 2, 3, 4

Hazardous to the aquatic environment — ►M2  long-term aquatic hazard (section 4.1) ◄

Hazardous to the aquatic environment — ►M2  long-term aquatic hazard (section 4.1) ◄ ►M2 ►M2 ►M2  ◄

1, 2, 3, 4

1, 2, 3, 4

▼M2 —————

▼M2 —————

▼M2 ————— ▼M2

▼M19

▼M19

▼M19 ▼M19

P280

Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…

Explosives (section 2.1)

Unstable explosive and divisions 1.1, 1.2, 1.3, 1.4, 1.5

Manufacturer/supplier to specify the appropriate type of personal protective equipment.

P280

P280

Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…

Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…

Explosives (section 2.1)

Explosives (section 2.1)

Unstable explosive and divisions 1.1, 1.2, 1.3, 1.4, 1.5

Unstable explosive and divisions 1.1, 1.2, 1.3, 1.4, 1.5

Manufacturer/supplier to specify the appropriate type of personal protective equipment.

Manufacturer/supplier to specify the appropriate type of personal protective equipment.

Flammable gases (section 2.2)

Pyrophoric gas

Flammable gases (section 2.2)

Flammable gases (section 2.2)

Pyrophoric gas

Pyrophoric gas

Flammable liquids (section 2.6)

1, 2, 3

Flammable liquids (section 2.6)

Flammable liquids (section 2.6)

1, 2, 3

1, 2, 3

Flammable solids (section 2.7)

1, 2

Flammable solids (section 2.7)

Flammable solids (section 2.7)

1, 2

1, 2

Self-reactive substances and mixtures (section 2.8)

Types A, B, C, D, E, F

Self-reactive substances and mixtures (section 2.8)

Self-reactive substances and mixtures (section 2.8)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

Pyrophoric liquids (section 2.9)

1

Pyrophoric liquids (section 2.9)

Pyrophoric liquids (section 2.9)

1

1

Pyrophoric solids (section 2.10)

1

Pyrophoric solids (section 2.10)

Pyrophoric solids (section 2.10)

1

1

Self-heating substances and mixtures (section 2.11)

1, 2

Self-heating substances and mixtures (section 2.11)

Self-heating substances and mixtures (section 2.11)

1, 2

1, 2

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

1, 2, 3

Oxidizing liquids (section 2.13)

1, 2, 3

Oxidizing liquids (section 2.13)

Oxidizing liquids (section 2.13)

1, 2, 3

1, 2, 3

Oxidizing solids (section 2.14)

1, 2, 3

Oxidizing solids (section 2.14)

Oxidizing solids (section 2.14)

1, 2, 3

1, 2, 3

Organic peroxides (section 2.15)

Types A, B, C, D, E, F

Organic peroxides (section 2.15)

Organic peroxides (section 2.15)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

Desensitised explosives (section 2.17)

1, 2, 3, 4

Desensitised explosives (section 2.17)

Desensitised explosives (section 2.17)

1, 2, 3, 4

1, 2, 3, 4

Acute toxicity – dermal (section 3.1)

1, 2, 3, 4

Manufacturer/supplier may further specify type of equipment where appropriate.

Acute toxicity – dermal (section 3.1)

Acute toxicity – dermal (section 3.1)

1, 2, 3, 4

1, 2, 3, 4

Manufacturer/supplier may further specify type of equipment where appropriate.

— Specify protective gloves/clothing. Specify protective gloves/clothing.

Manufacturer/supplier may further specify type of equipment where appropriate.

Skin corrosion (section 3.2)

1A, 1B, 1C

Manufacturer/supplier may further specify type of equipment where appropriate.

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

Manufacturer/supplier may further specify type of equipment where appropriate.

— Specify protective gloves/clothing and eye/face protection. Specify protective gloves/clothing and eye/face protection.

Manufacturer/supplier may further specify type of equipment where appropriate.

Skin irritation (section 3.2)

2

Manufacturer/supplier may further specify type of equipment where appropriate.

Skin irritation (section 3.2)

Skin irritation (section 3.2)

2

2

Manufacturer/supplier may further specify type of equipment where appropriate.

— Specify protective gloves. Specify protective gloves.

Manufacturer/supplier may further specify type of equipment where appropriate.

Skin sensitisation (section 3.4)

1, 1A, 1B

Skin sensitisation (section 3.4)

Skin sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

Serious eye damage (section 3.3)

1

Manufacturer/supplier may further specify type of equipment where appropriate.

Serious eye damage (section 3.3)

Serious eye damage (section 3.3)

1

1

Manufacturer/supplier may further specify type of equipment where appropriate.

— Specify eye/face protection. Specify eye/face protection.

Manufacturer/supplier may further specify type of equipment where appropriate.

Eye irritation (section 3.3)

2

Eye irritation (section 3.3)

Eye irritation (section 3.3)

2

2

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

Manufacturer/supplier to specify the appropriate type of personal protective equipment.

Germ cell mutagenicity (section 3.5)

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

1A, 1B, 2

Manufacturer/supplier to specify the appropriate type of personal protective equipment.

Manufacturer/supplier to specify the appropriate type of personal protective equipment.

Carcinogenicity (section 3.6)

1A, 1B, 2

Carcinogenicity (section 3.6)

Carcinogenicity (section 3.6)

1A, 1B, 2

1A, 1B, 2

Reproductive toxicity (section 3.7)

1A, 1B, 2

Reproductive toxicity (section 3.7)

Reproductive toxicity (section 3.7)

1A, 1B, 2

1A, 1B, 2

▼M4 —————

▼M4 —————

▼M4 ————— ▼M4

▼M12

▼M12

▼M12 ▼M12

P282

Wear cold insulating gloves and either face shield or eye protection.

Gases under pressure (Section 2.5)

Refrigerated liquefied gas

 

P282

P282

Wear cold insulating gloves and either face shield or eye protection.

Wear cold insulating gloves and either face shield or eye protection.

Gases under pressure (Section 2.5)

Gases under pressure (Section 2.5)

Refrigerated liquefied gas

Refrigerated liquefied gas

 

 

P283

Wear fire resistant or flame retardant clothing.

Oxidising liquids (Section 2.13)

1

 

P283

P283

Wear fire resistant or flame retardant clothing.

Wear fire resistant or flame retardant clothing.

Oxidising liquids (Section 2.13)

Oxidising liquids (Section 2.13)

1

1

 

 

Oxidising solids (Section 2.14)

1

 

Oxidising solids (Section 2.14)

Oxidising solids (Section 2.14)

1

1

 

 

P284

[In case of inadequate ventilation] wear respiratory protection.

Acute toxicity — inhalation (Section 3.1)

1, 2

—  text in square brackets may be used if additional information is provided with the chemical at the point of use that explains what type of ventilation would be adequate for safe use.

Manufacturer/supplier to specify equipment.

P284

P284

[In case of inadequate ventilation] wear respiratory protection.

[In case of inadequate ventilation] wear respiratory protection.

Acute toxicity — inhalation (Section 3.1)

Acute toxicity — inhalation (Section 3.1)

1, 2

1, 2

—  text in square brackets may be used if additional information is provided with the chemical at the point of use that explains what type of ventilation would be adequate for safe use.

Manufacturer/supplier to specify equipment.

—  text in square brackets may be used if additional information is provided with the chemical at the point of use that explains what type of ventilation would be adequate for safe use.

Manufacturer/supplier to specify equipment.

Respiratory sensitisation (Section 3.4)

1, 1A, 1B

Respiratory sensitisation (Section 3.4)

Respiratory sensitisation (Section 3.4)

1, 1A, 1B

1, 1A, 1B

▼M4 —————

▼M4 —————

▼M4 ————— ▼M4

▼M12

▼M12

▼M12 ▼M12

P231 + P232

Handle and store contents under inert gas/…

Protect from moisture.

Pyrophoric liquids (Section 2.9)

1

… Manufacturer/supplier to specify the appropriate liquid or gas if ‘inert gas’ is not appropriate.

P231 + P232

P231 + P232

Handle and store contents under inert gas/…

Protect from moisture.

Handle and store contents under inert gas/…

Protect from moisture.

Pyrophoric liquids (Section 2.9)

Pyrophoric liquids (Section 2.9)

1

1

… Manufacturer/supplier to specify the appropriate liquid or gas if ‘inert gas’ is not appropriate.

… Manufacturer/supplier to specify the appropriate liquid or gas if ‘inert gas’ is not appropriate.

Pyrophoric solids (Section 2.10)

1

Pyrophoric solids (Section 2.10)

Pyrophoric solids (Section 2.10)

1

1

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2, 3

—  if the substance or mixture reacts readily with moisture in air.

… Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate.

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2, 3

1, 2, 3

—  if the substance or mixture reacts readily with moisture in air.

… Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate.

—  if the substance or mixture reacts readily with moisture in air.

… Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate.

▼M12 —————

▼M12 —————

▼M12 ————— ▼M12

▼B

▼B

▼B ▼B

Table 6.3

Precautionary statements — Response

Code

Response precautionary statements

Hazard class

Hazard category

Conditions for use

(1)

(2)

(3)

(4)

(5)

▼M19

P301

IF SWALLOWED:

Acute toxicity – oral (section 3.1)

1, 2, 3, 4

 

Skin corrosion (section 3.2)

1, 1A, 1B, 1C

Aspiration Hazard (section 3.10)

1

P302

IF ON SKIN:

Pyrophoric liquids (section 2.9)

1

 

Pyrophoric solids (section 2.10)

1

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2

Acute toxicity – dermal (section 3.1)

1, 2, 3, 4

Skin irritation (section 3.2)

2

Skin sensitisation (section 3.4)

1, 1A, 1B

▼B

P303

IF ON SKIN (or hair):

Flammable liquids (section 2.6)

1, 2, 3

 

Skin corrosion (section 3.2)

1A, 1B, 1C

▼M2

P304

IF INHALED:

Acute toxicity — inhalation (section 3.1)

1, 2, 3, 4

 

Skin corrosion (section 3.2)

1A, 1B, 1C

Respiratory sensitisation (section 3.4)

1, 1A, 1B

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity — single exposure; narcosis (section 3.8)

3

▼B

P305

IF IN EYES:

Skin corrosion (section 3.2)

1A, 1B, 1C

 

Serious eye damage/eye irritation (section 3.3)

1

Eye irritation (section 3.3)

2

P306

IF ON CLOTHING:

Oxidising liquids (section 2.13)

1

 

Oxidising solids (section 2.14)

1

▼M4 —————

▼M4

P308

IF exposed or concerned:

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

 

Carcinogenicity (section 3.6)

1A, 1B, 2

Reproductive toxicity (section 3.7)

1A, 1B, 2

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Specific target organ toxicity, single exposure (section 3.8)

1, 2

▼M4 —————

▼M4

P310

Immediately call a POISON CENTER/doctor/…

Acute toxicity — oral (section 3.1)

1, 2, 3

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

Acute toxicity — dermal (section 3.1)

1, 2

Acute toxicity — inhalation (section 3.1)

1, 2

Skin corrosion (section 3.2)

1A, 1B, 1C

Serious eye damage/eye irritation (section 3.3)

1

Aspiration hazard (section 3.10)

1

P311

Call a POISON CENTER/doctor/…

Acute toxicity — inhalation (section 3.1)

3

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

Respiratory sensitisation (section 3.4)

1, 1A, 1B

Specific target organ toxicity — single exposure (section 3.8)

1, 2

▼M12

P312

Call a POISON CENTRE/doctor/… if you feel unwell.

Acute toxicity — oral (Section 3.1)

4

… Manufacturer/supplier to specify the appropriate source of emergency medical advice.

Acute toxicity — dermal (Section 3.1)

3, 4

Acute toxicity — inhalation (Section 3.1)

4

Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)

3

Specific target organ toxicity — single exposure; narcotic effects (Section 3.8)

3

▼M2

P313

Get medical advice/attention.

Skin irritation (section 3.2)

2, 3

 

Eye irritation (section 3.3)

2

Skin sensitisation (section 3.4)

1, 1A, 1B

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

Carcinogenicity (section 3.6)

1A, 1B, 2

Reproductive toxicity (section 3.7)

1A, 1B, 2

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

▼B

P314

Get medical advice/attention if you feel unwell.

Specific target organ toxicity — repeated exposure (section 3.9)

1, 2

 

P315

Get immediate medical advice/attention.

Gases under pressure (section 2.5)

Refrigerated liquefied gas

 

▼M12

P320

Specific treatment is urgent (see … on this label).

Acute toxicity — inhalation (Section 3.1)

1, 2

—  if immediate administration of antidote is required.

… Reference to supplemental first aid instruction.

P321

Specific treatment (see … on this label).

Acute toxicity — oral (Section 3.1)

1, 2, 3

—  if immediate administration of antidote is required.

… Reference to supplemental first aid instruction.

Acute toxicity, dermal (Section 3.1)

1, 2, 3, 4

—  if immediate measures such as specific cleansing agent are advised.

… Reference to supplemental first aid instruction.

Acute toxicity — inhalation (Section 3.1)

3

—  if immediate specific measures are required.

… Reference to supplemental first aid instruction.

Skin corrosion (Section 3.2)

1, 1A, 1B, 1C

… Reference to supplemental first aid instruction.

Manufacturer/supplier may specify a cleansing agent if appropriate.

Skin irritation (Section 3.2)

2

Skin sensitisation (Section 3.4)

1, 1A, 1B

Specific target organ toxicity — single exposure (Section 3.8)

1

—  if immediate measures are required.

… Reference to supplemental first aid instruction.

▼M4 —————

▼B

P330

Rinse mouth.

Acute toxicity — oral (section 3.1)

1, 2, 3, 4

 

Skin corrosion (section 3.2)

1A, 1B, 1C

P331

Do NOT induce vomiting.

Skin corrosion (section 3.2)

1A, 1B, 1C

 

Aspiration hazard (section 3.10)

1

▼M19

P332

If skin irritation occurs:

Skin irritation (section 3.2)

2

may be omitted if P333 is given on the label.

▼M2

P333

If skin irritation or rash occurs:

Skin sensitisation (section 3.4)

1, 1A, 1B

 

▼M12

P334

Immerse in cool water [or wrap in wet bandages].

Pyrophoric liquids (Section 2.9)

1

—  text in square brackets to be used for pyrophoric liquids and solids

Pyrophoric solids (Section 2.10)

1

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2

Use only ‘immerse in cool water.’ Text in square brackets should not be used.

▼B

P335

Brush off loose particles from skin.

Pyrophoric solids (section 2.10)

1

 

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2

P336

Thaw frosted parts with lukewarm water. Do not rub affected area.

Gases under pressure (section 2.5)

Refrigerated liquefied gas

 

P337

If eye irritation persists:

Eye irritation (section 3.3)

2

 

P338

Remove contact lenses, if present and easy to do. Continue rinsing.

Skin corrosion (section 3.2)

1A, 1B, 1C

 

Serious eye damage/eye irritation (section 3.3)

1

Eye irritation (section 3.3)

2

▼M4

P340

Remove person to fresh air and keep comfortable for breathing.

Acute toxicity — inhalation (section 3.1)

1, 2, 3, 4

 

Skin corrosion (section 3.2)

1A, 1B, 1C

Respiratory sensitisation (section 3.4)

1, 1A, 1B

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity — single exposure; narcosis (section 3.8)

3

▼M4 —————

▼M2

P342

If experiencing respiratory symptoms:

Respiratory sensitisation (section 3.4)

1, 1A, 1B

 

▼M4 —————

▼B

P351

Rinse cautiously with water for several minutes.

Skin corrosion (section 3.2)

1A, 1B, 1C

 

Serious eye damage/eye irritation (section 3.3)

1

Eye irritation (section 3.3)

2

▼M4

P352

Wash with plenty of water/…

Acute toxicity — dermal (section 3.1)

1, 2, 3, 4

…Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate.

Skin irritation (section 3.2)

2

Skin sensitisation (section 3.4)

1, 1A, 1B

▼M12

P353

Rinse skin with water [or shower].

Flammable liquids (Section 2.6)

1, 2, 3

—  text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical.

Skin corrosion (Section 3.2)

1, 1A, 1B, 1C

▼B

P360

Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.

Oxidising liquids (section 2.13)

1

 

Oxidising solids (section 2.14)

1

▼M4

P361

Take off immediately all contaminated clothing.

Flammable liquids (section 2.6)

1, 2, 3

 

Acute toxicity — dermal (section 3.1)

1, 2, 3

Skin corrosion (section 3.2)

1A, 1B, 1C

P362

Take off contaminated clothing.

Acute toxicity, dermal (section 3.1)

4

 

Skin irritation (section 3.2)

2

Skin sensitisation (section 3.4)

1, 1A, 1B

P363

Wash contaminated clothing before reuse.

Skin corrosion (section 3.2)

1A, 1B, 1C

 

▼M4

P364

And wash it before reuse.

Acute toxicity, dermal (section 3.1)

1, 2, 3, 4

 

Skin irritation (section 3.2)

2

 

Skin sensitisation (section 3.4)

1, 1A, 1B

 

▼M19

P370

In case of fire:

Explosives (section 2.1)

Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5

 

Oxidising gases (section 2.4)

1

Flammable liquids (section 2.6)

1, 2, 3

Flammable solids (section 2.7)

1, 2

Self-reactive substances and mixtures (section 2.8)

Types A, B, C, D, E, F

Pyrophoric liquids (section 2.9)

1

Pyrophoric solids (section 2.10)

1

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

Oxidising liquids (section 2.13)

1, 2, 3

Oxidising solids (section 2.14)

1, 2, 3

Organic Peroxides (section 2.15)

Types A, B, C, D, E, F

Desensitised explosives (section 2.17)

1, 2, 3

 

P371

In case of major fire and large quantities:

Oxidising liquids (section 2.13)

1

 

Oxidising solids (section 2.14)

1

 

Desensitised explosives (section 2.17)

4

 

▼M12

P372

Explosion risk.

Explosives (Section 2.1)

Unstable explosives and Divisions 1.1, 1.2, 1.3, and 1.5

 

Division 1.4

—  except for explosives of division 1.4 (compatibility group S) in transport packaging.

Self-reactive substances and mixtures (Section 2.8)

Type A

 

Organic peroxides (Section 2.15)

Type A

P373

DO NOT fight fire when fire reaches explosives.

Explosives (Section 2.1)

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.5

 

Division 1.4

—  except for explosives of division 1.4 (compatibility group S) in transport packaging.

Self-reactive substances and mixtures (Section 2.8)

Type A

 

Organic peroxides (Section 2.15)

Type A

▼M12 —————

▼M19

P375

Fight fire remotely due to the risk of explosion.

Explosives (section 2.1)

Division 1.4

Self-reactive substances and mixtures (section 2.8)

Type B

 

Oxidising liquids (section 2.13)

1

Oxidising solids (section 2.14)

1

Organic peroxides (section 2.15)

Type B

Desensitised explosives (section 2.17)

1, 2, 3, 4

▼B

P376

Stop leak if safe to do so.

Oxidising gases (section 2.4)

1

 

▼M19

P377

Leaking gas fire: Do not extinguish, unless leak can be stopped safely.

Flammable gases (section 2.2)

1A, 1B, 2

 

▼M12

P378

Use … to extinguish.

Flammable liquids (Section 2.6)

1, 2, 3

—  if water increases risk

… Manufacturer/supplier to specify appropriate media

Flammable solids (Section 2.7)

1, 2

Self-reactive substances and mixtures (Section 2.8)

Types B, C, D, E, F

Pyrophoric liquids (Section 2.9)

1

Pyrophoric solids (Section 2.10)

1

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2, 3

Oxidising liquids (Section 2.13)

1, 2, 3

Oxidising solids (Section 2.14)

1, 2, 3

Organic peroxides (Section 2.15)

Types B, C, D, E, F

▼M19

P380

Evacuate area.

Explosives (section 2.1)

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5

 

Self-reactive substances and mixtures (section 2.8)

Types A, B

 

Oxidising liquids (section 2.13)

1

 

Oxidising solids (section 2.14)

1

 

Organic peroxides (section 2.15)

Types A, B

 

Desensitised explosives (section 2.17)

1, 2, 3, 4

 

P381

In case of leakage, eliminate all ignition sources

Flammable gases (section 2.2)

1A, 1B, 2

 

▼B

P390

Absorb spillage to prevent material damage.

Corrosive to metals (section 2.16)

1

 

P391

Collect spillage.

Hazardous to the aquatic environment – acute aquatic hazard (section 4.1)

1

 

Hazardous to the aquatic environment – ►M2  long-term aquatic hazard (section 4.1) ◄

1, 2

▼M4

P301 + P310

IF SWALLOWED: Immediately call a POISON CENTER/doctor/…

Acute toxicity — oral (section 3.1)

1, 2, 3

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

Aspiration hazard (section 3.10)

1

▼M19

P301 + P312

IF SWALLOWED: Call a POISON CENTER/doctor/… if you feel unwell

Acute toxicity – oral (section 3.1)

4

… Manufacturer/supplier to specify the appropriate source of emergency medical advice

▼M12 —————

▼M12

P302 + P334

IF ON SKIN: Immerse in cool water or wrap in wet bandages.

Pyrophoric liquids (Section 2.9)

1

 

▼M4 —————

▼M4

P302 + P352

IF ON SKIN: Wash with plenty of water/…

Acute toxicity — dermal (section 3.1)

1, 2, 3, 4

…Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate.

Skin irritation (section 3.2)

2

Skin sensitisation (section 3.4)

1, 1A, 1B

▼M12 —————

▼M4

P304 + P340

IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Acute toxicity — inhalation (section 3.1)

1, 2, 3, 4

 

Skin corrosion (section 3.2)

1A, 1B, 1C

Respiratory sensitisation (section 3.4)

1, 1A, 1B

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity — single exposure; narcosis (section 3.8)

3

▼M4 —————

▼M12 —————

▼B

P306 + P360

IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.

Oxidising liquids (section 2.13)

1

 

Oxidising solids (section 2.14)

1

▼M4

P308 + P311

IF exposed or concerned: Call a POISON CENTER/doctor/…

Specific target organ toxicity — single exposure (section 3.8)

1, 2

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

▼B

P308 + P313

IF exposed or concerned: Get medical advice/attention.

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

 

Carcinogenicity (section 3.6)

1A, 1B, 2

Reproductive toxicity (section 3.7)

1A, 1B, 2

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

▼M4 —————

▼M12

P332 + P313

If skin irritation occurs: Get medical advice/attention.

Skin irritation (Section 3.2)

2

—  may be omitted when P333 + P313 is given on the label.

▼M2

P333 + P313

If skin irritation or rash occurs: Get medical advice/attention.

Skin sensitisation (section 3.4)

1, 1A, 1B

 

▼M12

P336 + P315

Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention.

Gases under pressure (Section 2.5)

Refrigerated liquefied gas

 

▼M12 —————

▼B

P337 + P313

If eye irritation persists: Get medical advice/attention.

Eye irritation (section 3.3)

2

 

▼M4

P342 + P311

If experiencing respiratory symptoms: Call a POISON CENTER/doctor/…

Respiratory sensitisation (section 3.4)

1, 1A, 1B

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

▼M4

P361 + P364

Take off immediately all contaminated clothing and wash it before reuse.

Acute toxicity, dermal (section 3.1)

1, 2, 3

 

P362 + P364

Take off contaminated clothing and wash it before reuse.

Acute toxicity, dermal (section 3.1)

4

 

Skin irritation (section 3.2)

2

Skin sensitisation (section 3.4)

1, 1A, 1B

▼B

P370 + P376

In case of fire: Stop leak if safe to do so.

Oxidizing gases (section 2.4)

1

 

▼M12

P370 + P378

In case of fire: Use … to extinguish.

Flammable liquids (Section 2.6)

1, 2, 3

—  if water increases risk.

… Manufacturer/sup-plier to specify appropriate media.

Flammable solids (Section 2.7)

1, 2

Self-reactive substances and mixtures (Section 2.8)

Types C, D, E, F

Pyrophoric liquids (Section 2.9)

1

Pyrophoric solids (Section 2.10)

1

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2, 3

Oxidising liquids (Section 2.13)

1, 2, 3

Oxidising solids (Section 2.14)

1, 2, 3

Organic peroxides (Section 2.15)

Types C, D, E, F

▼M12

P301 + P330 + P331

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

Skin corrosion (Section 3.2)

1, 1A, 1B, 1C

 

P302 + P335 + P334

IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].

Pyrophoric solids (Section 2.10)

1

—  text in square brackets to be used for pyrophoric solids

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2

—  use only ‘Immerse in cold water’. Text in square brackets should not be used.

P303 + P361 + P353

IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

Flammable liquids (Section 2.6)

1, 2, 3

—  text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical.

Skin corrosion (Section 3.2)

1, 1A, 1B, 1C

P305 + P351 + P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Skin corrosion (Section 3.2)

1, 1A, 1B, 1C

 

Serious eye damage/eye irritation (Section 3.3)

1

 

Eye irritation (Section 3.3)

2

 

▼M12 —————

▼M19

P370 + P380 + P375

In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.

Explosives (section 2.1)

Division 1.4

Desensitised explosives (section 2.17)

1, 2, 3

 

P371 + P380 + P375

In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.

Oxidising liquids (section 2.13)

1

 

Oxidising solids (section 2.14)

1

Desensitised explosives (section 2.17)

4

▼M12

P370 + P372 + P380 + P373

In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives

Explosives (Section 2.1)

Unstable explosives and divisions 1.1, 1.2, 1.3, 1.5

 

Division 1.4

—  except for explosives of division 1.4 (compatibility group S) in transport packaging.

Self-reactive substances and mixtures (Section 2.8)

Type A

 

Organic peroxides (Section 2.15)

Type A

 

P370 + P380 + P375 + [P378]

In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. [Use … to extinguish].

Self-reactive substances and mixtures (Section 2.8)

Type B

—  text in square brackets to be used if water increases risk.

… Manufacturer/supplier to specify appropriate media.

Organic peroxides (Section 2.15)

Type B

▼B

Code

Response precautionary statements

Hazard class

Hazard category

Conditions for use

Code

Code

Response precautionary statements

Response precautionary statements

Hazard class

Hazard class

Hazard category

Hazard category

Conditions for use

Conditions for use

(1)

(2)

(3)

(4)

(5)

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

(5)

(5)

▼M19

▼M19

▼M19 ▼M19

P301

IF SWALLOWED:

Acute toxicity – oral (section 3.1)

1, 2, 3, 4

 

P301

P301

IF SWALLOWED:

IF SWALLOWED:

Acute toxicity – oral (section 3.1)

Acute toxicity – oral (section 3.1)

1, 2, 3, 4

1, 2, 3, 4

 

 

Skin corrosion (section 3.2)

1, 1A, 1B, 1C

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1, 1A, 1B, 1C

1, 1A, 1B, 1C

Aspiration Hazard (section 3.10)

1

Aspiration Hazard (section 3.10)

Aspiration Hazard (section 3.10)

1

1

P302

IF ON SKIN:

Pyrophoric liquids (section 2.9)

1

 

P302

P302

IF ON SKIN:

IF ON SKIN:

Pyrophoric liquids (section 2.9)

Pyrophoric liquids (section 2.9)

1

1

 

 

Pyrophoric solids (section 2.10)

1

Pyrophoric solids (section 2.10)

Pyrophoric solids (section 2.10)

1

1

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2

1, 2

Acute toxicity – dermal (section 3.1)

1, 2, 3, 4

Acute toxicity – dermal (section 3.1)

Acute toxicity – dermal (section 3.1)

1, 2, 3, 4

1, 2, 3, 4

Skin irritation (section 3.2)

2

Skin irritation (section 3.2)

Skin irritation (section 3.2)

2

2

Skin sensitisation (section 3.4)

1, 1A, 1B

Skin sensitisation (section 3.4)

Skin sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

▼B

▼B

▼B ▼B

P303

IF ON SKIN (or hair):

Flammable liquids (section 2.6)

1, 2, 3

 

P303

P303

IF ON SKIN (or hair):

IF ON SKIN (or hair):

Flammable liquids (section 2.6)

Flammable liquids (section 2.6)

1, 2, 3

1, 2, 3

 

 

Skin corrosion (section 3.2)

1A, 1B, 1C

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

▼M2

▼M2

▼M2 ▼M2

P304

IF INHALED:

Acute toxicity — inhalation (section 3.1)

1, 2, 3, 4

 

P304

P304

IF INHALED:

IF INHALED:

Acute toxicity — inhalation (section 3.1)

Acute toxicity — inhalation (section 3.1)

1, 2, 3, 4

1, 2, 3, 4

 

 

Skin corrosion (section 3.2)

1A, 1B, 1C

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

Respiratory sensitisation (section 3.4)

1, 1A, 1B

Respiratory sensitisation (section 3.4)

Respiratory sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

3

3

Specific target organ toxicity — single exposure; narcosis (section 3.8)

3

Specific target organ toxicity — single exposure; narcosis (section 3.8)

Specific target organ toxicity — single exposure; narcosis (section 3.8)

3

3

▼B

▼B

▼B ▼B

P305

IF IN EYES:

Skin corrosion (section 3.2)

1A, 1B, 1C

 

P305

P305

IF IN EYES:

IF IN EYES:

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

 

 

Serious eye damage/eye irritation (section 3.3)

1

Serious eye damage/eye irritation (section 3.3)

Serious eye damage/eye irritation (section 3.3)

1

1

Eye irritation (section 3.3)

2

Eye irritation (section 3.3)

Eye irritation (section 3.3)

2

2

P306

IF ON CLOTHING:

Oxidising liquids (section 2.13)

1

 

P306

P306

IF ON CLOTHING:

IF ON CLOTHING:

Oxidising liquids (section 2.13)

Oxidising liquids (section 2.13)

1

1

 

 

Oxidising solids (section 2.14)

1

Oxidising solids (section 2.14)

Oxidising solids (section 2.14)

1

1

▼M4 —————

▼M4 —————

▼M4 ————— ▼M4

▼M4

▼M4

▼M4 ▼M4

P308

IF exposed or concerned:

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

 

P308

P308

IF exposed or concerned:

IF exposed or concerned:

Germ cell mutagenicity (section 3.5)

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

1A, 1B, 2

 

 

Carcinogenicity (section 3.6)

1A, 1B, 2

Carcinogenicity (section 3.6)

Carcinogenicity (section 3.6)

1A, 1B, 2

1A, 1B, 2

Reproductive toxicity (section 3.7)

1A, 1B, 2

Reproductive toxicity (section 3.7)

Reproductive toxicity (section 3.7)

1A, 1B, 2

1A, 1B, 2

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Reproductive toxicity — effects on or via lactation (section 3.7)

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Additional category

Specific target organ toxicity, single exposure (section 3.8)

1, 2

Specific target organ toxicity, single exposure (section 3.8)

Specific target organ toxicity, single exposure (section 3.8)

1, 2

1, 2

▼M4 —————

▼M4 —————

▼M4 ————— ▼M4

▼M4

▼M4

▼M4 ▼M4

P310

Immediately call a POISON CENTER/doctor/…

Acute toxicity — oral (section 3.1)

1, 2, 3

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

P310

P310

Immediately call a POISON CENTER/doctor/…

Immediately call a POISON CENTER/doctor/…

Acute toxicity — oral (section 3.1)

Acute toxicity — oral (section 3.1)

1, 2, 3

1, 2, 3

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

Acute toxicity — dermal (section 3.1)

1, 2

Acute toxicity — dermal (section 3.1)

Acute toxicity — dermal (section 3.1)

1, 2

1, 2

Acute toxicity — inhalation (section 3.1)

1, 2

Acute toxicity — inhalation (section 3.1)

Acute toxicity — inhalation (section 3.1)

1, 2

1, 2

Skin corrosion (section 3.2)

1A, 1B, 1C

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

Serious eye damage/eye irritation (section 3.3)

1

Serious eye damage/eye irritation (section 3.3)

Serious eye damage/eye irritation (section 3.3)

1

1

Aspiration hazard (section 3.10)

1

Aspiration hazard (section 3.10)

Aspiration hazard (section 3.10)

1

1

P311

Call a POISON CENTER/doctor/…

Acute toxicity — inhalation (section 3.1)

3

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

P311

P311

Call a POISON CENTER/doctor/…

Call a POISON CENTER/doctor/…

Acute toxicity — inhalation (section 3.1)

Acute toxicity — inhalation (section 3.1)

3

3

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

Respiratory sensitisation (section 3.4)

1, 1A, 1B

Respiratory sensitisation (section 3.4)

Respiratory sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

Specific target organ toxicity — single exposure (section 3.8)

1, 2

Specific target organ toxicity — single exposure (section 3.8)

Specific target organ toxicity — single exposure (section 3.8)

1, 2

1, 2

▼M12

▼M12

▼M12 ▼M12

P312

Call a POISON CENTRE/doctor/… if you feel unwell.

Acute toxicity — oral (Section 3.1)

4

… Manufacturer/supplier to specify the appropriate source of emergency medical advice.

P312

P312

Call a POISON CENTRE/doctor/… if you feel unwell.

Call a POISON CENTRE/doctor/… if you feel unwell.

Acute toxicity — oral (Section 3.1)

Acute toxicity — oral (Section 3.1)

4

4

… Manufacturer/supplier to specify the appropriate source of emergency medical advice.

… Manufacturer/supplier to specify the appropriate source of emergency medical advice.

Acute toxicity — dermal (Section 3.1)

3, 4

Acute toxicity — dermal (Section 3.1)

Acute toxicity — dermal (Section 3.1)

3, 4

3, 4

Acute toxicity — inhalation (Section 3.1)

4

Acute toxicity — inhalation (Section 3.1)

Acute toxicity — inhalation (Section 3.1)

4

4

Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)

3

Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)

Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)

3

3

Specific target organ toxicity — single exposure; narcotic effects (Section 3.8)

3

Specific target organ toxicity — single exposure; narcotic effects (Section 3.8)

Specific target organ toxicity — single exposure; narcotic effects (Section 3.8)

3

3

▼M2

▼M2

▼M2 ▼M2

P313

Get medical advice/attention.

Skin irritation (section 3.2)

2, 3

 

P313

P313

Get medical advice/attention.

Get medical advice/attention.

Skin irritation (section 3.2)

Skin irritation (section 3.2)

2, 3

2, 3

 

 

Eye irritation (section 3.3)

2

Eye irritation (section 3.3)

Eye irritation (section 3.3)

2

2

Skin sensitisation (section 3.4)

1, 1A, 1B

Skin sensitisation (section 3.4)

Skin sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

Germ cell mutagenicity (section 3.5)

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

1A, 1B, 2

Carcinogenicity (section 3.6)

1A, 1B, 2

Carcinogenicity (section 3.6)

Carcinogenicity (section 3.6)

1A, 1B, 2

1A, 1B, 2

Reproductive toxicity (section 3.7)

1A, 1B, 2

Reproductive toxicity (section 3.7)

Reproductive toxicity (section 3.7)

1A, 1B, 2

1A, 1B, 2

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Reproductive toxicity — effects on or via lactation (section 3.7)

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Additional category

▼B

▼B

▼B ▼B

P314

Get medical advice/attention if you feel unwell.

Specific target organ toxicity — repeated exposure (section 3.9)

1, 2

 

P314

P314

Get medical advice/attention if you feel unwell.

Get medical advice/attention if you feel unwell.

Specific target organ toxicity — repeated exposure (section 3.9)

Specific target organ toxicity — repeated exposure (section 3.9)

1, 2

1, 2

 

 

P315

Get immediate medical advice/attention.

Gases under pressure (section 2.5)

Refrigerated liquefied gas

 

P315

P315

Get immediate medical advice/attention.

Get immediate medical advice/attention.

Gases under pressure (section 2.5)

Gases under pressure (section 2.5)

Refrigerated liquefied gas

Refrigerated liquefied gas

 

 

▼M12

▼M12

▼M12 ▼M12

P320

Specific treatment is urgent (see … on this label).

Acute toxicity — inhalation (Section 3.1)

1, 2

—  if immediate administration of antidote is required.

… Reference to supplemental first aid instruction.

P320

P320

Specific treatment is urgent (see … on this label).

Specific treatment is urgent (see … on this label).

Acute toxicity — inhalation (Section 3.1)

Acute toxicity — inhalation (Section 3.1)

1, 2

1, 2

—  if immediate administration of antidote is required.

… Reference to supplemental first aid instruction.

—  if immediate administration of antidote is required.

… Reference to supplemental first aid instruction.

P321

Specific treatment (see … on this label).

Acute toxicity — oral (Section 3.1)

1, 2, 3

—  if immediate administration of antidote is required.

… Reference to supplemental first aid instruction.

P321

P321

Specific treatment (see … on this label).

Specific treatment (see … on this label).

Acute toxicity — oral (Section 3.1)

Acute toxicity — oral (Section 3.1)

1, 2, 3

1, 2, 3

—  if immediate administration of antidote is required.

… Reference to supplemental first aid instruction.

—  if immediate administration of antidote is required.

… Reference to supplemental first aid instruction.

Acute toxicity, dermal (Section 3.1)

1, 2, 3, 4

—  if immediate measures such as specific cleansing agent are advised.

… Reference to supplemental first aid instruction.

Acute toxicity, dermal (Section 3.1)

Acute toxicity, dermal (Section 3.1)

1, 2, 3, 4

1, 2, 3, 4

—  if immediate measures such as specific cleansing agent are advised.

… Reference to supplemental first aid instruction.

—  if immediate measures such as specific cleansing agent are advised.

… Reference to supplemental first aid instruction.

Acute toxicity — inhalation (Section 3.1)

3

—  if immediate specific measures are required.

… Reference to supplemental first aid instruction.

Acute toxicity — inhalation (Section 3.1)

Acute toxicity — inhalation (Section 3.1)

3

3

—  if immediate specific measures are required.

… Reference to supplemental first aid instruction.

—  if immediate specific measures are required.

… Reference to supplemental first aid instruction.

Skin corrosion (Section 3.2)

1, 1A, 1B, 1C

… Reference to supplemental first aid instruction.

Manufacturer/supplier may specify a cleansing agent if appropriate.

Skin corrosion (Section 3.2)

Skin corrosion (Section 3.2)

1, 1A, 1B, 1C

1, 1A, 1B, 1C

… Reference to supplemental first aid instruction.

Manufacturer/supplier may specify a cleansing agent if appropriate.

… Reference to supplemental first aid instruction.

Manufacturer/supplier may specify a cleansing agent if appropriate.

Skin irritation (Section 3.2)

2

Skin irritation (Section 3.2)

Skin irritation (Section 3.2)

2

2

Skin sensitisation (Section 3.4)

1, 1A, 1B

Skin sensitisation (Section 3.4)

Skin sensitisation (Section 3.4)

1, 1A, 1B

1, 1A, 1B

Specific target organ toxicity — single exposure (Section 3.8)

1

—  if immediate measures are required.

… Reference to supplemental first aid instruction.

Specific target organ toxicity — single exposure (Section 3.8)

Specific target organ toxicity — single exposure (Section 3.8)

1

1

—  if immediate measures are required.

… Reference to supplemental first aid instruction.

—  if immediate measures are required.

… Reference to supplemental first aid instruction.

▼M4 —————

▼M4 —————

▼M4 ————— ▼M4

▼B

▼B

▼B ▼B

P330

Rinse mouth.

Acute toxicity — oral (section 3.1)

1, 2, 3, 4

 

P330

P330

Rinse mouth.

Rinse mouth.

Acute toxicity — oral (section 3.1)

Acute toxicity — oral (section 3.1)

1, 2, 3, 4

1, 2, 3, 4

 

 

Skin corrosion (section 3.2)

1A, 1B, 1C

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

P331

Do NOT induce vomiting.

Skin corrosion (section 3.2)

1A, 1B, 1C

 

P331

P331

Do NOT induce vomiting.

Do NOT induce vomiting.

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

 

 

Aspiration hazard (section 3.10)

1

Aspiration hazard (section 3.10)

Aspiration hazard (section 3.10)

1

1

▼M19

▼M19

▼M19 ▼M19

P332

If skin irritation occurs:

Skin irritation (section 3.2)

2

may be omitted if P333 is given on the label.

P332

P332

If skin irritation occurs:

If skin irritation occurs:

Skin irritation (section 3.2)

Skin irritation (section 3.2)

2

2

may be omitted if P333 is given on the label.

may be omitted if P333 is given on the label.

▼M2

▼M2

▼M2 ▼M2

P333

If skin irritation or rash occurs:

Skin sensitisation (section 3.4)

1, 1A, 1B

 

P333

P333

If skin irritation or rash occurs:

If skin irritation or rash occurs:

Skin sensitisation (section 3.4)

Skin sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

 

 

▼M12

▼M12

▼M12 ▼M12

P334

Immerse in cool water [or wrap in wet bandages].

Pyrophoric liquids (Section 2.9)

1

—  text in square brackets to be used for pyrophoric liquids and solids

P334

P334

Immerse in cool water [or wrap in wet bandages].

Immerse in cool water [or wrap in wet bandages].

Pyrophoric liquids (Section 2.9)

Pyrophoric liquids (Section 2.9)

1

1

—  text in square brackets to be used for pyrophoric liquids and solids

—  text in square brackets to be used for pyrophoric liquids and solids

Pyrophoric solids (Section 2.10)

1

Pyrophoric solids (Section 2.10)

Pyrophoric solids (Section 2.10)

1

1

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2

Use only ‘immerse in cool water.’ Text in square brackets should not be used.

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2

1, 2

Use only ‘immerse in cool water.’ Text in square brackets should not be used.

Use only ‘immerse in cool water.’ Text in square brackets should not be used.

▼B

▼B

▼B ▼B

P335

Brush off loose particles from skin.

Pyrophoric solids (section 2.10)

1

 

P335

P335

Brush off loose particles from skin.

Brush off loose particles from skin.

Pyrophoric solids (section 2.10)

Pyrophoric solids (section 2.10)

1

1

 

 

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2

1, 2

P336

Thaw frosted parts with lukewarm water. Do not rub affected area.

Gases under pressure (section 2.5)

Refrigerated liquefied gas

 

P336

P336

Thaw frosted parts with lukewarm water. Do not rub affected area.

Thaw frosted parts with lukewarm water. Do not rub affected area.

Gases under pressure (section 2.5)

Gases under pressure (section 2.5)

Refrigerated liquefied gas

Refrigerated liquefied gas

 

 

P337

If eye irritation persists:

Eye irritation (section 3.3)

2

 

P337

P337

If eye irritation persists:

If eye irritation persists:

Eye irritation (section 3.3)

Eye irritation (section 3.3)

2

2

 

 

P338

Remove contact lenses, if present and easy to do. Continue rinsing.

Skin corrosion (section 3.2)

1A, 1B, 1C

 

P338

P338

Remove contact lenses, if present and easy to do. Continue rinsing.

Remove contact lenses, if present and easy to do. Continue rinsing.

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

 

 

Serious eye damage/eye irritation (section 3.3)

1

Serious eye damage/eye irritation (section 3.3)

Serious eye damage/eye irritation (section 3.3)

1

1

Eye irritation (section 3.3)

2

Eye irritation (section 3.3)

Eye irritation (section 3.3)

2

2

▼M4

▼M4

▼M4 ▼M4

P340

Remove person to fresh air and keep comfortable for breathing.

Acute toxicity — inhalation (section 3.1)

1, 2, 3, 4

 

P340

P340

Remove person to fresh air and keep comfortable for breathing.

Remove person to fresh air and keep comfortable for breathing.

Acute toxicity — inhalation (section 3.1)

Acute toxicity — inhalation (section 3.1)

1, 2, 3, 4

1, 2, 3, 4

 

 

Skin corrosion (section 3.2)

1A, 1B, 1C

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

Respiratory sensitisation (section 3.4)

1, 1A, 1B

Respiratory sensitisation (section 3.4)

Respiratory sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

3

3

Specific target organ toxicity — single exposure; narcosis (section 3.8)

3

Specific target organ toxicity — single exposure; narcosis (section 3.8)

Specific target organ toxicity — single exposure; narcosis (section 3.8)

3

3

▼M4 —————

▼M4 —————

▼M4 ————— ▼M4

▼M2

▼M2

▼M2 ▼M2

P342

If experiencing respiratory symptoms:

Respiratory sensitisation (section 3.4)

1, 1A, 1B

 

P342

P342

If experiencing respiratory symptoms:

If experiencing respiratory symptoms:

Respiratory sensitisation (section 3.4)

Respiratory sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

 

 

▼M4 —————

▼M4 —————

▼M4 ————— ▼M4

▼B

▼B

▼B ▼B

P351

Rinse cautiously with water for several minutes.

Skin corrosion (section 3.2)

1A, 1B, 1C

 

P351

P351

Rinse cautiously with water for several minutes.

Rinse cautiously with water for several minutes.

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

 

 

Serious eye damage/eye irritation (section 3.3)

1

Serious eye damage/eye irritation (section 3.3)

Serious eye damage/eye irritation (section 3.3)

1

1

Eye irritation (section 3.3)

2

Eye irritation (section 3.3)

Eye irritation (section 3.3)

2

2

▼M4

▼M4

▼M4 ▼M4

P352

Wash with plenty of water/…

Acute toxicity — dermal (section 3.1)

1, 2, 3, 4

…Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate.

P352

P352

Wash with plenty of water/…

Wash with plenty of water/…

Acute toxicity — dermal (section 3.1)

Acute toxicity — dermal (section 3.1)

1, 2, 3, 4

1, 2, 3, 4

…Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate.

…Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate.

Skin irritation (section 3.2)

2

Skin irritation (section 3.2)

Skin irritation (section 3.2)

2

2

Skin sensitisation (section 3.4)

1, 1A, 1B

Skin sensitisation (section 3.4)

Skin sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

▼M12

▼M12

▼M12 ▼M12

P353

Rinse skin with water [or shower].

Flammable liquids (Section 2.6)

1, 2, 3

—  text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical.

P353

P353

Rinse skin with water [or shower].

Rinse skin with water [or shower].

Flammable liquids (Section 2.6)

Flammable liquids (Section 2.6)

1, 2, 3

1, 2, 3

—  text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical.

—  text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical.

Skin corrosion (Section 3.2)

1, 1A, 1B, 1C

Skin corrosion (Section 3.2)

Skin corrosion (Section 3.2)

1, 1A, 1B, 1C

1, 1A, 1B, 1C

▼B

▼B

▼B ▼B

P360

Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.

Oxidising liquids (section 2.13)

1

 

P360

P360

Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.

Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.

Oxidising liquids (section 2.13)

Oxidising liquids (section 2.13)

1

1

 

 

Oxidising solids (section 2.14)

1

Oxidising solids (section 2.14)

Oxidising solids (section 2.14)

1

1

▼M4

▼M4

▼M4 ▼M4

P361

Take off immediately all contaminated clothing.

Flammable liquids (section 2.6)

1, 2, 3

 

P361

P361

Take off immediately all contaminated clothing.

Take off immediately all contaminated clothing.

Flammable liquids (section 2.6)

Flammable liquids (section 2.6)

1, 2, 3

1, 2, 3

 

 

Acute toxicity — dermal (section 3.1)

1, 2, 3

Acute toxicity — dermal (section 3.1)

Acute toxicity — dermal (section 3.1)

1, 2, 3

1, 2, 3

Skin corrosion (section 3.2)

1A, 1B, 1C

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

P362

Take off contaminated clothing.

Acute toxicity, dermal (section 3.1)

4

 

P362

P362

Take off contaminated clothing.

Take off contaminated clothing.

Acute toxicity, dermal (section 3.1)

Acute toxicity, dermal (section 3.1)

4

4

 

 

Skin irritation (section 3.2)

2

Skin irritation (section 3.2)

Skin irritation (section 3.2)

2

2

Skin sensitisation (section 3.4)

1, 1A, 1B

Skin sensitisation (section 3.4)

Skin sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

P363

Wash contaminated clothing before reuse.

Skin corrosion (section 3.2)

1A, 1B, 1C

 

P363

P363

Wash contaminated clothing before reuse.

Wash contaminated clothing before reuse.

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

 

 

▼M4

▼M4

▼M4 ▼M4

P364

And wash it before reuse.

Acute toxicity, dermal (section 3.1)

1, 2, 3, 4

 

P364

P364

And wash it before reuse.

And wash it before reuse.

Acute toxicity, dermal (section 3.1)

Acute toxicity, dermal (section 3.1)

1, 2, 3, 4

1, 2, 3, 4

 

 

Skin irritation (section 3.2)

2

 

Skin irritation (section 3.2)

Skin irritation (section 3.2)

2

2

 

 

Skin sensitisation (section 3.4)

1, 1A, 1B

 

Skin sensitisation (section 3.4)

Skin sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

 

 

▼M19

▼M19

▼M19 ▼M19

P370

In case of fire:

Explosives (section 2.1)

Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5

 

P370

P370

In case of fire:

In case of fire:

Explosives (section 2.1)

Explosives (section 2.1)

Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5

Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5

 

 

Oxidising gases (section 2.4)

1

Oxidising gases (section 2.4)

Oxidising gases (section 2.4)

1

1

Flammable liquids (section 2.6)

1, 2, 3

Flammable liquids (section 2.6)

Flammable liquids (section 2.6)

1, 2, 3

1, 2, 3

Flammable solids (section 2.7)

1, 2

Flammable solids (section 2.7)

Flammable solids (section 2.7)

1, 2

1, 2

Self-reactive substances and mixtures (section 2.8)

Types A, B, C, D, E, F

Self-reactive substances and mixtures (section 2.8)

Self-reactive substances and mixtures (section 2.8)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

Pyrophoric liquids (section 2.9)

1

Pyrophoric liquids (section 2.9)

Pyrophoric liquids (section 2.9)

1

1

Pyrophoric solids (section 2.10)

1

Pyrophoric solids (section 2.10)

Pyrophoric solids (section 2.10)

1

1

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

1, 2, 3

Oxidising liquids (section 2.13)

1, 2, 3

Oxidising liquids (section 2.13)

Oxidising liquids (section 2.13)

1, 2, 3

1, 2, 3

Oxidising solids (section 2.14)

1, 2, 3

Oxidising solids (section 2.14)

Oxidising solids (section 2.14)

1, 2, 3

1, 2, 3

Organic Peroxides (section 2.15)

Types A, B, C, D, E, F

Organic Peroxides (section 2.15)

Organic Peroxides (section 2.15)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

Desensitised explosives (section 2.17)

1, 2, 3

 

Desensitised explosives (section 2.17)

Desensitised explosives (section 2.17)

1, 2, 3

1, 2, 3

 

 

P371

In case of major fire and large quantities:

Oxidising liquids (section 2.13)

1

 

P371

P371

In case of major fire and large quantities:

In case of major fire and large quantities:

Oxidising liquids (section 2.13)

Oxidising liquids (section 2.13)

1

1

 

 

Oxidising solids (section 2.14)

1

 

Oxidising solids (section 2.14)

Oxidising solids (section 2.14)

1

1

 

 

Desensitised explosives (section 2.17)

4

 

Desensitised explosives (section 2.17)

Desensitised explosives (section 2.17)

4

4

 

 

▼M12

▼M12

▼M12 ▼M12

P372

Explosion risk.

Explosives (Section 2.1)

Unstable explosives and Divisions 1.1, 1.2, 1.3, and 1.5

 

P372

P372

Explosion risk.

Explosion risk.

Explosives (Section 2.1)

Explosives (Section 2.1)

Unstable explosives and Divisions 1.1, 1.2, 1.3, and 1.5

Unstable explosives and Divisions 1.1, 1.2, 1.3, and 1.5

 

 

Division 1.4

—  except for explosives of division 1.4 (compatibility group S) in transport packaging.

Division 1.4

Division 1.4

—  except for explosives of division 1.4 (compatibility group S) in transport packaging.

—  except for explosives of division 1.4 (compatibility group S) in transport packaging.

Self-reactive substances and mixtures (Section 2.8)

Type A

 

Self-reactive substances and mixtures (Section 2.8)

Self-reactive substances and mixtures (Section 2.8)

Type A

Type A

 

 

Organic peroxides (Section 2.15)

Type A

Organic peroxides (Section 2.15)

Organic peroxides (Section 2.15)

Type A

Type A

P373

DO NOT fight fire when fire reaches explosives.

Explosives (Section 2.1)

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.5

 

P373

P373

DO NOT fight fire when fire reaches explosives.

DO NOT fight fire when fire reaches explosives.

Explosives (Section 2.1)

Explosives (Section 2.1)

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.5

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.5

 

 

Division 1.4

—  except for explosives of division 1.4 (compatibility group S) in transport packaging.

Division 1.4

Division 1.4

—  except for explosives of division 1.4 (compatibility group S) in transport packaging.

—  except for explosives of division 1.4 (compatibility group S) in transport packaging.

Self-reactive substances and mixtures (Section 2.8)

Type A

 

Self-reactive substances and mixtures (Section 2.8)

Self-reactive substances and mixtures (Section 2.8)

Type A

Type A

 

 

Organic peroxides (Section 2.15)

Type A

Organic peroxides (Section 2.15)

Organic peroxides (Section 2.15)

Type A

Type A

▼M12 —————

▼M12 —————

▼M12 ————— ▼M12

▼M19

▼M19

▼M19 ▼M19

P375

Fight fire remotely due to the risk of explosion.

Explosives (section 2.1)

Division 1.4

P375

P375

Fight fire remotely due to the risk of explosion.

Fight fire remotely due to the risk of explosion.

Explosives (section 2.1)

Explosives (section 2.1)

Division 1.4

Division 1.4

— for explosives of division 1.4 (compatibility group S) in transport packaging.

Self-reactive substances and mixtures (section 2.8)

Type B

 

Self-reactive substances and mixtures (section 2.8)

Self-reactive substances and mixtures (section 2.8)

Type B

Type B

 

 

Oxidising liquids (section 2.13)

1

Oxidising liquids (section 2.13)

Oxidising liquids (section 2.13)

1

1

Oxidising solids (section 2.14)

1

Oxidising solids (section 2.14)

Oxidising solids (section 2.14)

1

1

Organic peroxides (section 2.15)

Type B

Organic peroxides (section 2.15)

Organic peroxides (section 2.15)

Type B

Type B

Desensitised explosives (section 2.17)

1, 2, 3, 4

Desensitised explosives (section 2.17)

Desensitised explosives (section 2.17)

1, 2, 3, 4

1, 2, 3, 4

▼B

▼B

▼B ▼B

P376

Stop leak if safe to do so.

Oxidising gases (section 2.4)

1

 

P376

P376

Stop leak if safe to do so.

Stop leak if safe to do so.

Oxidising gases (section 2.4)

Oxidising gases (section 2.4)

1

1

 

 

▼M19

▼M19

▼M19 ▼M19

P377

Leaking gas fire: Do not extinguish, unless leak can be stopped safely.

Flammable gases (section 2.2)

1A, 1B, 2

 

P377

P377

Leaking gas fire: Do not extinguish, unless leak can be stopped safely.

Leaking gas fire: Do not extinguish, unless leak can be stopped safely.

Flammable gases (section 2.2)

Flammable gases (section 2.2)

1A, 1B, 2

1A, 1B, 2

 

 

▼M12

▼M12

▼M12 ▼M12

P378

Use … to extinguish.

Flammable liquids (Section 2.6)

1, 2, 3

—  if water increases risk

… Manufacturer/supplier to specify appropriate media

P378

P378

Use … to extinguish.

Use … to extinguish.

Flammable liquids (Section 2.6)

Flammable liquids (Section 2.6)

1, 2, 3

1, 2, 3

—  if water increases risk

… Manufacturer/supplier to specify appropriate media

—  if water increases risk

… Manufacturer/supplier to specify appropriate media

Flammable solids (Section 2.7)

1, 2

Flammable solids (Section 2.7)

Flammable solids (Section 2.7)

1, 2

1, 2

Self-reactive substances and mixtures (Section 2.8)

Types B, C, D, E, F

Self-reactive substances and mixtures (Section 2.8)

Self-reactive substances and mixtures (Section 2.8)

Types B, C, D, E, F

Types B, C, D, E, F

Pyrophoric liquids (Section 2.9)

1

Pyrophoric liquids (Section 2.9)

Pyrophoric liquids (Section 2.9)

1

1

Pyrophoric solids (Section 2.10)

1

Pyrophoric solids (Section 2.10)

Pyrophoric solids (Section 2.10)

1

1

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2, 3

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2, 3

1, 2, 3

Oxidising liquids (Section 2.13)

1, 2, 3

Oxidising liquids (Section 2.13)

Oxidising liquids (Section 2.13)

1, 2, 3

1, 2, 3

Oxidising solids (Section 2.14)

1, 2, 3

Oxidising solids (Section 2.14)

Oxidising solids (Section 2.14)

1, 2, 3

1, 2, 3

Organic peroxides (Section 2.15)

Types B, C, D, E, F

Organic peroxides (Section 2.15)

Organic peroxides (Section 2.15)

Types B, C, D, E, F

Types B, C, D, E, F

▼M19

▼M19

▼M19 ▼M19

P380

Evacuate area.

Explosives (section 2.1)

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5

 

P380

P380

Evacuate area.

Evacuate area.

Explosives (section 2.1)

Explosives (section 2.1)

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5

 

 

Self-reactive substances and mixtures (section 2.8)

Types A, B

 

Self-reactive substances and mixtures (section 2.8)

Self-reactive substances and mixtures (section 2.8)

Types A, B

Types A, B

 

 

Oxidising liquids (section 2.13)

1

 

Oxidising liquids (section 2.13)

Oxidising liquids (section 2.13)

1

1

 

 

Oxidising solids (section 2.14)

1

 

Oxidising solids (section 2.14)

Oxidising solids (section 2.14)

1

1

 

 

Organic peroxides (section 2.15)

Types A, B

 

Organic peroxides (section 2.15)

Organic peroxides (section 2.15)

Types A, B

Types A, B

 

 

Desensitised explosives (section 2.17)

1, 2, 3, 4

 

Desensitised explosives (section 2.17)

Desensitised explosives (section 2.17)

1, 2, 3, 4

1, 2, 3, 4

 

 

P381

In case of leakage, eliminate all ignition sources

Flammable gases (section 2.2)

1A, 1B, 2

 

P381

P381

In case of leakage, eliminate all ignition sources

In case of leakage, eliminate all ignition sources

Flammable gases (section 2.2)

Flammable gases (section 2.2)

1A, 1B, 2

1A, 1B, 2

 

 

▼B

▼B

▼B ▼B

P390

Absorb spillage to prevent material damage.

Corrosive to metals (section 2.16)

1

 

P390

P390

Absorb spillage to prevent material damage.

Absorb spillage to prevent material damage.

Corrosive to metals (section 2.16)

Corrosive to metals (section 2.16)

1

1

 

 

P391

Collect spillage.

Hazardous to the aquatic environment – acute aquatic hazard (section 4.1)

1

 

P391

P391

Collect spillage.

Collect spillage.

Hazardous to the aquatic environment – acute aquatic hazard (section 4.1)

Hazardous to the aquatic environment – acute aquatic hazard (section 4.1)

1

1

 

 

Hazardous to the aquatic environment – ►M2  long-term aquatic hazard (section 4.1) ◄

1, 2

Hazardous to the aquatic environment – ►M2  long-term aquatic hazard (section 4.1) ◄

Hazardous to the aquatic environment – ►M2  long-term aquatic hazard (section 4.1) ◄ ►M2 ►M2 ►M2  ◄

1, 2

1, 2

▼M4

▼M4

▼M4 ▼M4

P301 + P310

IF SWALLOWED: Immediately call a POISON CENTER/doctor/…

Acute toxicity — oral (section 3.1)

1, 2, 3

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

P301 + P310

P301 + P310

IF SWALLOWED: Immediately call a POISON CENTER/doctor/…

IF SWALLOWED: Immediately call a POISON CENTER/doctor/…

Acute toxicity — oral (section 3.1)

Acute toxicity — oral (section 3.1)

1, 2, 3

1, 2, 3

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

Aspiration hazard (section 3.10)

1

Aspiration hazard (section 3.10)

Aspiration hazard (section 3.10)

1

1

▼M19

▼M19

▼M19 ▼M19

P301 + P312

IF SWALLOWED: Call a POISON CENTER/doctor/… if you feel unwell

Acute toxicity – oral (section 3.1)

4

… Manufacturer/supplier to specify the appropriate source of emergency medical advice

P301 + P312

P301 + P312

IF SWALLOWED: Call a POISON CENTER/doctor/… if you feel unwell

IF SWALLOWED: Call a POISON CENTER/doctor/… if you feel unwell

Acute toxicity – oral (section 3.1)

Acute toxicity – oral (section 3.1)

4

4

… Manufacturer/supplier to specify the appropriate source of emergency medical advice

… Manufacturer/supplier to specify the appropriate source of emergency medical advice

▼M12 —————

▼M12 —————

▼M12 ————— ▼M12

▼M12

▼M12

▼M12 ▼M12

P302 + P334

IF ON SKIN: Immerse in cool water or wrap in wet bandages.

Pyrophoric liquids (Section 2.9)

1

 

P302 + P334

P302 + P334

IF ON SKIN: Immerse in cool water or wrap in wet bandages.

IF ON SKIN: Immerse in cool water or wrap in wet bandages.

Pyrophoric liquids (Section 2.9)

Pyrophoric liquids (Section 2.9)

1

1

 

 

▼M4 —————

▼M4 —————

▼M4 ————— ▼M4

▼M4

▼M4

▼M4 ▼M4

P302 + P352

IF ON SKIN: Wash with plenty of water/…

Acute toxicity — dermal (section 3.1)

1, 2, 3, 4

…Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate.

P302 + P352

P302 + P352

IF ON SKIN: Wash with plenty of water/…

IF ON SKIN: Wash with plenty of water/…

Acute toxicity — dermal (section 3.1)

Acute toxicity — dermal (section 3.1)

1, 2, 3, 4

1, 2, 3, 4

…Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate.

…Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate.

Skin irritation (section 3.2)

2

Skin irritation (section 3.2)

Skin irritation (section 3.2)

2

2

Skin sensitisation (section 3.4)

1, 1A, 1B

Skin sensitisation (section 3.4)

Skin sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

▼M12 —————

▼M12 —————

▼M12 ————— ▼M12

▼M4

▼M4

▼M4 ▼M4

P304 + P340

IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Acute toxicity — inhalation (section 3.1)

1, 2, 3, 4

 

P304 + P340

P304 + P340

IF INHALED: Remove person to fresh air and keep comfortable for breathing.

IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Acute toxicity — inhalation (section 3.1)

Acute toxicity — inhalation (section 3.1)

1, 2, 3, 4

1, 2, 3, 4

 

 

Skin corrosion (section 3.2)

1A, 1B, 1C

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

Respiratory sensitisation (section 3.4)

1, 1A, 1B

Respiratory sensitisation (section 3.4)

Respiratory sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

3

3

Specific target organ toxicity — single exposure; narcosis (section 3.8)

3

Specific target organ toxicity — single exposure; narcosis (section 3.8)

Specific target organ toxicity — single exposure; narcosis (section 3.8)

3

3

▼M4 —————

▼M4 —————

▼M4 ————— ▼M4

▼M12 —————

▼M12 —————

▼M12 ————— ▼M12

▼B

▼B

▼B ▼B

P306 + P360

IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.

Oxidising liquids (section 2.13)

1

 

P306 + P360

P306 + P360

IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.

IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.

Oxidising liquids (section 2.13)

Oxidising liquids (section 2.13)

1

1

 

 

Oxidising solids (section 2.14)

1

Oxidising solids (section 2.14)

Oxidising solids (section 2.14)

1

1

▼M4

▼M4

▼M4 ▼M4

P308 + P311

IF exposed or concerned: Call a POISON CENTER/doctor/…

Specific target organ toxicity — single exposure (section 3.8)

1, 2

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

P308 + P311

P308 + P311

IF exposed or concerned: Call a POISON CENTER/doctor/…

IF exposed or concerned: Call a POISON CENTER/doctor/…

Specific target organ toxicity — single exposure (section 3.8)

Specific target organ toxicity — single exposure (section 3.8)

1, 2

1, 2

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

▼B

▼B

▼B ▼B

P308 + P313

IF exposed or concerned: Get medical advice/attention.

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

 

P308 + P313

P308 + P313

IF exposed or concerned: Get medical advice/attention.

IF exposed or concerned: Get medical advice/attention.

Germ cell mutagenicity (section 3.5)

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

1A, 1B, 2

 

 

Carcinogenicity (section 3.6)

1A, 1B, 2

Carcinogenicity (section 3.6)

Carcinogenicity (section 3.6)

1A, 1B, 2

1A, 1B, 2

Reproductive toxicity (section 3.7)

1A, 1B, 2

Reproductive toxicity (section 3.7)

Reproductive toxicity (section 3.7)

1A, 1B, 2

1A, 1B, 2

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Reproductive toxicity — effects on or via lactation (section 3.7)

Reproductive toxicity — effects on or via lactation (section 3.7)

Additional category

Additional category

▼M4 —————

▼M4 —————

▼M4 ————— ▼M4

▼M12

▼M12

▼M12 ▼M12

P332 + P313

If skin irritation occurs: Get medical advice/attention.

Skin irritation (Section 3.2)

2

—  may be omitted when P333 + P313 is given on the label.

P332 + P313

P332 + P313

If skin irritation occurs: Get medical advice/attention.

If skin irritation occurs: Get medical advice/attention.

Skin irritation (Section 3.2)

Skin irritation (Section 3.2)

2

2

—  may be omitted when P333 + P313 is given on the label.

—  may be omitted when P333 + P313 is given on the label.

▼M2

▼M2

▼M2 ▼M2

P333 + P313

If skin irritation or rash occurs: Get medical advice/attention.

Skin sensitisation (section 3.4)

1, 1A, 1B

 

P333 + P313

P333 + P313

If skin irritation or rash occurs: Get medical advice/attention.

If skin irritation or rash occurs: Get medical advice/attention.

Skin sensitisation (section 3.4)

Skin sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

 

 

▼M12

▼M12

▼M12 ▼M12

P336 + P315

Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention.

Gases under pressure (Section 2.5)

Refrigerated liquefied gas

 

P336 + P315

P336 + P315

Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention.

Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention.

Gases under pressure (Section 2.5)

Gases under pressure (Section 2.5)

Refrigerated liquefied gas

Refrigerated liquefied gas

 

 

▼M12 —————

▼M12 —————

▼M12 ————— ▼M12

▼B

▼B

▼B ▼B

P337 + P313

If eye irritation persists: Get medical advice/attention.

Eye irritation (section 3.3)

2

 

P337 + P313

P337 + P313

If eye irritation persists: Get medical advice/attention.

If eye irritation persists: Get medical advice/attention.

Eye irritation (section 3.3)

Eye irritation (section 3.3)

2

2

 

 

▼M4

▼M4

▼M4 ▼M4

P342 + P311

If experiencing respiratory symptoms: Call a POISON CENTER/doctor/…

Respiratory sensitisation (section 3.4)

1, 1A, 1B

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

P342 + P311

P342 + P311

If experiencing respiratory symptoms: Call a POISON CENTER/doctor/…

If experiencing respiratory symptoms: Call a POISON CENTER/doctor/…

Respiratory sensitisation (section 3.4)

Respiratory sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

…Manufacturer/supplier to specify the appropriate source of emergency medical advice.

▼M4

▼M4

▼M4 ▼M4

P361 + P364

Take off immediately all contaminated clothing and wash it before reuse.

Acute toxicity, dermal (section 3.1)

1, 2, 3

 

P361 + P364

P361 + P364

Take off immediately all contaminated clothing and wash it before reuse.

Take off immediately all contaminated clothing and wash it before reuse.

Acute toxicity, dermal (section 3.1)

Acute toxicity, dermal (section 3.1)

1, 2, 3

1, 2, 3

 

 

P362 + P364

Take off contaminated clothing and wash it before reuse.

Acute toxicity, dermal (section 3.1)

4

 

P362 + P364

P362 + P364

Take off contaminated clothing and wash it before reuse.

Take off contaminated clothing and wash it before reuse.

Acute toxicity, dermal (section 3.1)

Acute toxicity, dermal (section 3.1)

4

4

 

 

Skin irritation (section 3.2)

2

Skin irritation (section 3.2)

Skin irritation (section 3.2)

2

2

Skin sensitisation (section 3.4)

1, 1A, 1B

Skin sensitisation (section 3.4)

Skin sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

▼B

▼B

▼B ▼B

P370 + P376

In case of fire: Stop leak if safe to do so.

Oxidizing gases (section 2.4)

1

 

P370 + P376

P370 + P376

In case of fire: Stop leak if safe to do so.

In case of fire: Stop leak if safe to do so.

Oxidizing gases (section 2.4)

Oxidizing gases (section 2.4)

1

1

 

 

▼M12

▼M12

▼M12 ▼M12

P370 + P378

In case of fire: Use … to extinguish.

Flammable liquids (Section 2.6)

1, 2, 3

—  if water increases risk.

… Manufacturer/sup-plier to specify appropriate media.

P370 + P378

P370 + P378

In case of fire: Use … to extinguish.

In case of fire: Use … to extinguish.

Flammable liquids (Section 2.6)

Flammable liquids (Section 2.6)

1, 2, 3

1, 2, 3

—  if water increases risk.

… Manufacturer/sup-plier to specify appropriate media.

—  if water increases risk.

… Manufacturer/sup-plier to specify appropriate media.

Flammable solids (Section 2.7)

1, 2

Flammable solids (Section 2.7)

Flammable solids (Section 2.7)

1, 2

1, 2

Self-reactive substances and mixtures (Section 2.8)

Types C, D, E, F

Self-reactive substances and mixtures (Section 2.8)

Self-reactive substances and mixtures (Section 2.8)

Types C, D, E, F

Types C, D, E, F

Pyrophoric liquids (Section 2.9)

1

Pyrophoric liquids (Section 2.9)

Pyrophoric liquids (Section 2.9)

1

1

Pyrophoric solids (Section 2.10)

1

Pyrophoric solids (Section 2.10)

Pyrophoric solids (Section 2.10)

1

1

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2, 3

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2, 3

1, 2, 3

Oxidising liquids (Section 2.13)

1, 2, 3

Oxidising liquids (Section 2.13)

Oxidising liquids (Section 2.13)

1, 2, 3

1, 2, 3

Oxidising solids (Section 2.14)

1, 2, 3

Oxidising solids (Section 2.14)

Oxidising solids (Section 2.14)

1, 2, 3

1, 2, 3

Organic peroxides (Section 2.15)

Types C, D, E, F

Organic peroxides (Section 2.15)

Organic peroxides (Section 2.15)

Types C, D, E, F

Types C, D, E, F

▼M12

▼M12

▼M12 ▼M12

P301 + P330 + P331

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

Skin corrosion (Section 3.2)

1, 1A, 1B, 1C

 

P301 + P330 + P331

P301 + P330 + P331

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

Skin corrosion (Section 3.2)

Skin corrosion (Section 3.2)

1, 1A, 1B, 1C

1, 1A, 1B, 1C

 

 

P302 + P335 + P334

IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].

Pyrophoric solids (Section 2.10)

1

—  text in square brackets to be used for pyrophoric solids

P302 + P335 + P334

P302 + P335 + P334

IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].

IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].

Pyrophoric solids (Section 2.10)

Pyrophoric solids (Section 2.10)

1

1

—  text in square brackets to be used for pyrophoric solids

—  text in square brackets to be used for pyrophoric solids

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2

—  use only ‘Immerse in cold water’. Text in square brackets should not be used.

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)

1, 2

1, 2

—  use only ‘Immerse in cold water’. Text in square brackets should not be used.

—  use only ‘Immerse in cold water’. Text in square brackets should not be used.

P303 + P361 + P353

IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

Flammable liquids (Section 2.6)

1, 2, 3

—  text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical.

P303 + P361 + P353

P303 + P361 + P353

IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

Flammable liquids (Section 2.6)

Flammable liquids (Section 2.6)

1, 2, 3

1, 2, 3

—  text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical.

—  text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical.

Skin corrosion (Section 3.2)

1, 1A, 1B, 1C

Skin corrosion (Section 3.2)

Skin corrosion (Section 3.2)

1, 1A, 1B, 1C

1, 1A, 1B, 1C

P305 + P351 + P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Skin corrosion (Section 3.2)

1, 1A, 1B, 1C

 

P305 + P351 + P338

P305 + P351 + P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Skin corrosion (Section 3.2)

Skin corrosion (Section 3.2)

1, 1A, 1B, 1C

1, 1A, 1B, 1C

 

 

Serious eye damage/eye irritation (Section 3.3)

1

 

Serious eye damage/eye irritation (Section 3.3)

Serious eye damage/eye irritation (Section 3.3)

1

1

 

 

Eye irritation (Section 3.3)

2

 

Eye irritation (Section 3.3)

Eye irritation (Section 3.3)

2

2

 

 

▼M12 —————

▼M12 —————

▼M12 ————— ▼M12

▼M19

▼M19

▼M19 ▼M19

P370 + P380 + P375

In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.

Explosives (section 2.1)

Division 1.4

P370 + P380 + P375

P370 + P380 + P375

In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.

In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.

Explosives (section 2.1)

Explosives (section 2.1)

Division 1.4

Division 1.4

— for explosives of division 1.4 (compatibility group S) in transport packaging

Desensitised explosives (section 2.17)

1, 2, 3

 

Desensitised explosives (section 2.17)

Desensitised explosives (section 2.17)

1, 2, 3

1, 2, 3

 

 

P371 + P380 + P375

In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.

Oxidising liquids (section 2.13)

1

 

P371 + P380 + P375

P371 + P380 + P375

In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.

In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.

Oxidising liquids (section 2.13)

Oxidising liquids (section 2.13)

1

1

 

 

Oxidising solids (section 2.14)

1

Oxidising solids (section 2.14)

Oxidising solids (section 2.14)

1

1

Desensitised explosives (section 2.17)

4

Desensitised explosives (section 2.17)

Desensitised explosives (section 2.17)

4

4

▼M12

▼M12

▼M12 ▼M12

P370 + P372 + P380 + P373

In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives

Explosives (Section 2.1)

Unstable explosives and divisions 1.1, 1.2, 1.3, 1.5

 

P370 + P372 + P380 + P373

P370 + P372 + P380 + P373

In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives

In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives

Explosives (Section 2.1)

Explosives (Section 2.1)

Unstable explosives and divisions 1.1, 1.2, 1.3, 1.5

Unstable explosives and divisions 1.1, 1.2, 1.3, 1.5

 

 

Division 1.4

—  except for explosives of division 1.4 (compatibility group S) in transport packaging.

Division 1.4

Division 1.4

—  except for explosives of division 1.4 (compatibility group S) in transport packaging.

—  except for explosives of division 1.4 (compatibility group S) in transport packaging.

Self-reactive substances and mixtures (Section 2.8)

Type A

 

Self-reactive substances and mixtures (Section 2.8)

Self-reactive substances and mixtures (Section 2.8)

Type A

Type A

 

 

Organic peroxides (Section 2.15)

Type A

 

Organic peroxides (Section 2.15)

Organic peroxides (Section 2.15)

Type A

Type A

 

 

P370 + P380 + P375 + [P378]

In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. [Use … to extinguish].

Self-reactive substances and mixtures (Section 2.8)

Type B

—  text in square brackets to be used if water increases risk.

… Manufacturer/supplier to specify appropriate media.

P370 + P380 + P375 + [P378]

P370 + P380 + P375 + [P378]

In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. [Use … to extinguish].

In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. [Use … to extinguish].

Self-reactive substances and mixtures (Section 2.8)

Self-reactive substances and mixtures (Section 2.8)

Type B

Type B

—  text in square brackets to be used if water increases risk.

… Manufacturer/supplier to specify appropriate media.

—  text in square brackets to be used if water increases risk.

… Manufacturer/supplier to specify appropriate media.

Organic peroxides (Section 2.15)

Type B

Organic peroxides (Section 2.15)

Organic peroxides (Section 2.15)

Type B

Type B

▼B

▼B

▼B ▼B

Table 6.4

Precautionary statements — Storage

Code

Storage precautionary statements

Hazard class

Hazard category

Conditions for use

(1)

(2)

(3)

(4)

(5)

▼M19

P401

Store in accordance with …

Explosives (section 2.1)

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5

… Manufacturer/supplier to specify local/regional/national/international regulations as applicable.

Desensitised explosives (section 2.17)

1, 2, 3, 4

▼B

P402

Store in a dry place.

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

 

▼M19

P403

Store in a well-ventilated place.

Flammable gases (section 2.2)

1A, 1B, 2

 

Oxidising gases (section 2.4)

1

Gases under pressure (section 2.5)

Compressed gas

Liquefied gas

Refrigerated liquefied gas

Dissolved gas

Flammable liquids (section 2.6)

1, 2, 3

Self-reactive substances and mixtures (section 2.8)

Types A, B, C, D, E, F

Organic peroxides (section 2.15)

Acute toxicity – inhalation (section 3.1)

1, 2, 3

Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity – single exposure; narcotic effects (section 3.8)

3

▼B

P404

Store in a closed container.

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

 

P405

Store locked up.

Acute toxicity — oral (section 3.1)

1, 2, 3

 

Acute toxicity — dermal (section 3.1)

1, 2, 3

Acute toxicity — inhalation (section 3.1)

1, 2, 3

Skin corrosion (section 3.2)

1A, 1B, 1C

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

Carcinogenicity (section 3.6)

1A, 1B, 2

Reproductive toxicity (section 3.7)

1A, 1B, 2

Specific target organ toxicity — single exposure (section 3.8)

1, 2

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity — single exposure; narcosis (section 3.8)

3

Aspiration hazard (section 3.10)

1

▼M12

P406

Store in a corrosion-resistant/… container with a resistant inner liner.

Corrosive to metals (Section 2.16)

1

—  may be omitted if P234 is given on the label

… Manufacturer/supplier to specify other compatible materials.

P407

Maintain air gap between stacks or pallets.

Self-heating substances and mixtures (Section 2.11)

1, 2

 

▼M4

P410

Protect from sunlight.

Aerosols (section 2.3)

1,2, 3

 

Gases under pressure (section 2.5)

Compressed gas

Liquefied gas

Dissolved gas

—  may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, Model Regulations, unless those gases are subject to (slow) decomposition or polymerisation

Self-heating substances and mixtures (section 2.11)

1, 2

 

Organic peroxides (section 2.15)

Types A, B, C, D, E, F

 

▼M12

P411

Store at temperatures not exceeding … °C/… °F.

Self-reactive substances and mixtures (Section 2.8)

Types A, B, C, D, E, F

—  if temperature control is required (according to Annex I, Section 2.8.2.4 or 2.15.2.3) or if otherwise deemed necessary.

… Manufacturer/supplier to specify temperature using the applicable temperature scale.

Organic peroxides (Section 2.15)

Types A, B, C, D, E, F

P412

Do not expose to temperatures exceeding 50 °C/ 122 °F.

Aerosols (Section 2.3)

1, 2, 3

Manufacturer/supplier to use applicable temperature scale.

P413

Store bulk masses greater than … kg/… lbs at temperatures not exceeding … °C/… °F.

Self-heating substances and mixtures (Section 2.11)

1, 2

… Manufacturer/supplier to specify mass and temperature using applicable scale.

P420

Store separately.

Self-reactive substances and mixtures (Section 2.8)

Types A, B, C, D, E, F

 

Self-heating substances and mixtures (Section 2.11)

1,2

Oxidising liquids (Section 2.13)

1

Oxidising solids (Section 2.14)

1

Organic peroxides (Section 2.15)

Types A,B,C,D,E,F

▼M12 —————

▼B

P402 + P404

Store in a dry place. Store in a closed container.

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

 

▼M12

P403 + P233

Store in a well-ventilated place. Keep container tightly closed.

Acute toxicity — inhalation (Section 3.1)

1, 2, 3

—  if the substance or mixture is volatile and may generate a hazardous atmosphere.

Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)

3

Specific target organ toxicity — single exposure; narcosis (Section 3.8)

3

P403 + P235

Store in a well-ventilated place. Keep cool.

Flammable liquids (Section 2.6)

1, 2, 3

—  for flammable liquids Category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere.

P410 + P403

Protect from sunlight. Store in a well-ventilated place.

Gases under pressure (Section 2.5)

Compressed gas

—  P410 may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, unless those gases are subject to (slow) decomposition or polymerisation.

Liquefied gas

Dissolved gas

P410 + P412

Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.

Aerosols (Section 2.3)

1, 2, 3

Manufacturer/ supplier to use applicable temperature scale.

▼M12 —————

Code

Storage precautionary statements

Hazard class

Hazard category

Conditions for use

Code

Code

Storage precautionary statements

Storage precautionary statements

Hazard class

Hazard class

Hazard category

Hazard category

Conditions for use

Conditions for use

(1)

(2)

(3)

(4)

(5)

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

(5)

(5)

▼M19

▼M19

▼M19 ▼M19

P401

Store in accordance with …

Explosives (section 2.1)

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5

… Manufacturer/supplier to specify local/regional/national/international regulations as applicable.

P401

P401

Store in accordance with …

Store in accordance with …

Explosives (section 2.1)

Explosives (section 2.1)

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5

… Manufacturer/supplier to specify local/regional/national/international regulations as applicable.

… Manufacturer/supplier to specify local/regional/national/international regulations as applicable.

Desensitised explosives (section 2.17)

1, 2, 3, 4

Desensitised explosives (section 2.17)

Desensitised explosives (section 2.17)

1, 2, 3, 4

1, 2, 3, 4

▼B

▼B

▼B ▼B

P402

Store in a dry place.

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

 

P402

P402

Store in a dry place.

Store in a dry place.

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

1, 2, 3

 

 

▼M19

▼M19

▼M19 ▼M19

P403

Store in a well-ventilated place.

Flammable gases (section 2.2)

1A, 1B, 2

 

P403

P403

Store in a well-ventilated place.

Store in a well-ventilated place.

Flammable gases (section 2.2)

Flammable gases (section 2.2)

1A, 1B, 2

1A, 1B, 2

 

 

Oxidising gases (section 2.4)

1

Oxidising gases (section 2.4)

Oxidising gases (section 2.4)

1

1

Gases under pressure (section 2.5)

Compressed gas

Gases under pressure (section 2.5)

Gases under pressure (section 2.5)

Compressed gas

Compressed gas

Liquefied gas

Liquefied gas

Liquefied gas

Refrigerated liquefied gas

Refrigerated liquefied gas

Refrigerated liquefied gas

Dissolved gas

Dissolved gas

Dissolved gas

Flammable liquids (section 2.6)

1, 2, 3

Flammable liquids (section 2.6)

Flammable liquids (section 2.6)

1, 2, 3

1, 2, 3

— for flammable liquids Category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere.

Self-reactive substances and mixtures (section 2.8)

Types A, B, C, D, E, F

Self-reactive substances and mixtures (section 2.8)

Self-reactive substances and mixtures (section 2.8)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

— except for temperature controlled self-reactive substances and mixtures or organic peroxides because condensation and consequent freezing may take place.

Organic peroxides (section 2.15)

Organic peroxides (section 2.15)

Organic peroxides (section 2.15)

Acute toxicity – inhalation (section 3.1)

1, 2, 3

Acute toxicity – inhalation (section 3.1)

Acute toxicity – inhalation (section 3.1)

1, 2, 3

1, 2, 3

— if the substance or mixture is volatile and may generate a hazardous atmosphere.

Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8)

Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8)

3

3

Specific target organ toxicity – single exposure; narcotic effects (section 3.8)

3

Specific target organ toxicity – single exposure; narcotic effects (section 3.8)

Specific target organ toxicity – single exposure; narcotic effects (section 3.8)

3

3

▼B

▼B

▼B ▼B

P404

Store in a closed container.

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

 

P404

P404

Store in a closed container.

Store in a closed container.

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

1, 2, 3

 

 

P405

Store locked up.

Acute toxicity — oral (section 3.1)

1, 2, 3

 

P405

P405

Store locked up.

Store locked up.

Acute toxicity — oral (section 3.1)

Acute toxicity — oral (section 3.1)

1, 2, 3

1, 2, 3

 

 

Acute toxicity — dermal (section 3.1)

1, 2, 3

Acute toxicity — dermal (section 3.1)

Acute toxicity — dermal (section 3.1)

1, 2, 3

1, 2, 3

Acute toxicity — inhalation (section 3.1)

1, 2, 3

Acute toxicity — inhalation (section 3.1)

Acute toxicity — inhalation (section 3.1)

1, 2, 3

1, 2, 3

Skin corrosion (section 3.2)

1A, 1B, 1C

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1A, 1B, 1C

1A, 1B, 1C

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

Germ cell mutagenicity (section 3.5)

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

1A, 1B, 2

Carcinogenicity (section 3.6)

1A, 1B, 2

Carcinogenicity (section 3.6)

Carcinogenicity (section 3.6)

1A, 1B, 2

1A, 1B, 2

Reproductive toxicity (section 3.7)

1A, 1B, 2

Reproductive toxicity (section 3.7)

Reproductive toxicity (section 3.7)

1A, 1B, 2

1A, 1B, 2

Specific target organ toxicity — single exposure (section 3.8)

1, 2

Specific target organ toxicity — single exposure (section 3.8)

Specific target organ toxicity — single exposure (section 3.8)

1, 2

1, 2

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8)

3

3

Specific target organ toxicity — single exposure; narcosis (section 3.8)

3

Specific target organ toxicity — single exposure; narcosis (section 3.8)

Specific target organ toxicity — single exposure; narcosis (section 3.8)

3

3

Aspiration hazard (section 3.10)

1

Aspiration hazard (section 3.10)

Aspiration hazard (section 3.10)

1

1

▼M12

▼M12

▼M12 ▼M12

P406

Store in a corrosion-resistant/… container with a resistant inner liner.

Corrosive to metals (Section 2.16)

1

—  may be omitted if P234 is given on the label

… Manufacturer/supplier to specify other compatible materials.

P406

P406

Store in a corrosion-resistant/… container with a resistant inner liner.

Store in a corrosion-resistant/… container with a resistant inner liner.

Corrosive to metals (Section 2.16)

Corrosive to metals (Section 2.16)

1

1

—  may be omitted if P234 is given on the label

… Manufacturer/supplier to specify other compatible materials.

—  may be omitted if P234 is given on the label

… Manufacturer/supplier to specify other compatible materials.

P407

Maintain air gap between stacks or pallets.

Self-heating substances and mixtures (Section 2.11)

1, 2

 

P407

P407

Maintain air gap between stacks or pallets.

Maintain air gap between stacks or pallets.

Self-heating substances and mixtures (Section 2.11)

Self-heating substances and mixtures (Section 2.11)

1, 2

1, 2

 

 

▼M4

▼M4

▼M4 ▼M4

P410

Protect from sunlight.

Aerosols (section 2.3)

1,2, 3

 

P410

P410

Protect from sunlight.

Protect from sunlight.

Aerosols (section 2.3)

Aerosols (section 2.3)

1,2, 3

1,2, 3

 

 

Gases under pressure (section 2.5)

Compressed gas

Liquefied gas

Dissolved gas

—  may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, Model Regulations, unless those gases are subject to (slow) decomposition or polymerisation

Gases under pressure (section 2.5)

Gases under pressure (section 2.5)

Compressed gas

Liquefied gas

Dissolved gas

Compressed gas

Liquefied gas

Dissolved gas

—  may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, Model Regulations, unless those gases are subject to (slow) decomposition or polymerisation

—  may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, Model Regulations, unless those gases are subject to (slow) decomposition or polymerisation may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, Model Regulations, unless those gases are subject to (slow) decomposition or polymerisation

Self-heating substances and mixtures (section 2.11)

1, 2

 

Self-heating substances and mixtures (section 2.11)

Self-heating substances and mixtures (section 2.11)

1, 2

1, 2

 

 

Organic peroxides (section 2.15)

Types A, B, C, D, E, F

 

Organic peroxides (section 2.15)

Organic peroxides (section 2.15)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

 

 

▼M12

▼M12

▼M12 ▼M12

P411

Store at temperatures not exceeding … °C/… °F.

Self-reactive substances and mixtures (Section 2.8)

Types A, B, C, D, E, F

—  if temperature control is required (according to Annex I, Section 2.8.2.4 or 2.15.2.3) or if otherwise deemed necessary.

… Manufacturer/supplier to specify temperature using the applicable temperature scale.

P411

P411

Store at temperatures not exceeding … °C/… °F.

Store at temperatures not exceeding … °C/… °F.

Self-reactive substances and mixtures (Section 2.8)

Self-reactive substances and mixtures (Section 2.8)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

—  if temperature control is required (according to Annex I, Section 2.8.2.4 or 2.15.2.3) or if otherwise deemed necessary.

… Manufacturer/supplier to specify temperature using the applicable temperature scale.

—  if temperature control is required (according to Annex I, Section 2.8.2.4 or 2.15.2.3) or if otherwise deemed necessary.

… Manufacturer/supplier to specify temperature using the applicable temperature scale.

Organic peroxides (Section 2.15)

Types A, B, C, D, E, F

Organic peroxides (Section 2.15)

Organic peroxides (Section 2.15)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

P412

Do not expose to temperatures exceeding 50 °C/ 122 °F.

Aerosols (Section 2.3)

1, 2, 3

Manufacturer/supplier to use applicable temperature scale.

P412

P412

Do not expose to temperatures exceeding 50 °C/ 122 °F.

Do not expose to temperatures exceeding 50 °C/ 122 °F.

Aerosols (Section 2.3)

Aerosols (Section 2.3)

1, 2, 3

1, 2, 3

Manufacturer/supplier to use applicable temperature scale.

Manufacturer/supplier to use applicable temperature scale.

P413

Store bulk masses greater than … kg/… lbs at temperatures not exceeding … °C/… °F.

Self-heating substances and mixtures (Section 2.11)

1, 2

… Manufacturer/supplier to specify mass and temperature using applicable scale.

P413

P413

Store bulk masses greater than … kg/… lbs at temperatures not exceeding … °C/… °F.

Store bulk masses greater than … kg/… lbs at temperatures not exceeding … °C/… °F.

Self-heating substances and mixtures (Section 2.11)

Self-heating substances and mixtures (Section 2.11)

1, 2

1, 2

… Manufacturer/supplier to specify mass and temperature using applicable scale.

… Manufacturer/supplier to specify mass and temperature using applicable scale.

P420

Store separately.

Self-reactive substances and mixtures (Section 2.8)

Types A, B, C, D, E, F

 

P420

P420

Store separately.

Store separately.

Self-reactive substances and mixtures (Section 2.8)

Self-reactive substances and mixtures (Section 2.8)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

 

 

Self-heating substances and mixtures (Section 2.11)

1,2

Self-heating substances and mixtures (Section 2.11)

Self-heating substances and mixtures (Section 2.11)

1,2

1,2

Oxidising liquids (Section 2.13)

1

Oxidising liquids (Section 2.13)

Oxidising liquids (Section 2.13)

1

1

Oxidising solids (Section 2.14)

1

Oxidising solids (Section 2.14)

Oxidising solids (Section 2.14)

1

1

Organic peroxides (Section 2.15)

Types A,B,C,D,E,F

Organic peroxides (Section 2.15)

Organic peroxides (Section 2.15)

Types A,B,C,D,E,F

Types A,B,C,D,E,F

▼M12 —————

▼M12 —————

▼M12 ————— ▼M12

▼B

▼B

▼B ▼B

P402 + P404

Store in a dry place. Store in a closed container.

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

 

P402 + P404

P402 + P404

Store in a dry place. Store in a closed container.

Store in a dry place. Store in a closed container.

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

1, 2, 3

 

 

▼M12

▼M12

▼M12 ▼M12

P403 + P233

Store in a well-ventilated place. Keep container tightly closed.

Acute toxicity — inhalation (Section 3.1)

1, 2, 3

—  if the substance or mixture is volatile and may generate a hazardous atmosphere.

P403 + P233

P403 + P233

Store in a well-ventilated place. Keep container tightly closed.

Store in a well-ventilated place. Keep container tightly closed.

Acute toxicity — inhalation (Section 3.1)

Acute toxicity — inhalation (Section 3.1)

1, 2, 3

1, 2, 3

—  if the substance or mixture is volatile and may generate a hazardous atmosphere.

—  if the substance or mixture is volatile and may generate a hazardous atmosphere.

Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)

3

Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)

Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)

3

3

Specific target organ toxicity — single exposure; narcosis (Section 3.8)

3

Specific target organ toxicity — single exposure; narcosis (Section 3.8)

Specific target organ toxicity — single exposure; narcosis (Section 3.8)

3

3

P403 + P235

Store in a well-ventilated place. Keep cool.

Flammable liquids (Section 2.6)

1, 2, 3

—  for flammable liquids Category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere.

P403 + P235

P403 + P235

Store in a well-ventilated place. Keep cool.

Store in a well-ventilated place. Keep cool.

Flammable liquids (Section 2.6)

Flammable liquids (Section 2.6)

1, 2, 3

1, 2, 3

—  for flammable liquids Category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere.

—  for flammable liquids Category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere.

P410 + P403

Protect from sunlight. Store in a well-ventilated place.

Gases under pressure (Section 2.5)

Compressed gas

—  P410 may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, unless those gases are subject to (slow) decomposition or polymerisation.

P410 + P403

P410 + P403

Protect from sunlight. Store in a well-ventilated place.

Protect from sunlight. Store in a well-ventilated place.

Gases under pressure (Section 2.5)

Gases under pressure (Section 2.5)

Compressed gas

Compressed gas

—  P410 may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, unless those gases are subject to (slow) decomposition or polymerisation.

—  P410 may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, unless those gases are subject to (slow) decomposition or polymerisation.

Liquefied gas

Liquefied gas

Liquefied gas

Dissolved gas

Dissolved gas

Dissolved gas

P410 + P412

Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.

Aerosols (Section 2.3)

1, 2, 3

Manufacturer/ supplier to use applicable temperature scale.

P410 + P412

P410 + P412

Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.

Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.

Aerosols (Section 2.3)

Aerosols (Section 2.3)

1, 2, 3

1, 2, 3

Manufacturer/ supplier to use applicable temperature scale.

Manufacturer/ supplier to use applicable temperature scale.

▼M12 —————

▼M12 —————

▼M12 ————— ▼M12

▼M2 ▼M2

Table 6.5

Precautionary statements — Disposal

Code

Disposal precautionary statements

Hazard class

Hazard category

Conditions for use

(1)

(2)

(3)

(4)

(5)

▼M19

P501

Dispose of contents/container to …

Flammable liquids (section 2.6)

1, 2, 3

… in accordance with local/regional/national/international regulation (to be specified).

Manufacturer/supplier to specify whether disposal requirements apply to contents, container or both.

Self-reactive substances and mixtures (section 2.8)

Types A, B, C, D, E, F

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

Oxidising liquids (section 2.13)

1, 2, 3

Oxidising solids (section 2.14)

1, 2, 3

Organic peroxides (section 2.15)

Types A, B, C, D, E, F

Desensitised explosives (section 2.17)

1, 2, 3, 4

Acute toxicity – oral (section 3.1)

1, 2, 3, 4

Acute toxicity – dermal (section 3.1)

1, 2, 3, 4

Acute toxicity – inhalation (section 3.1)

1, 2, 3

Skin corrosion (section 3.2)

1, 1A, 1B, 1C

Respiratory sensitisation (section 3.4)

1, 1A, 1B

Skin sensitisation (section 3.4)

1, 1A, 1B

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

Carcinogenicity (section 3.6)

1A, 1B, 2

Reproductive toxicity (section 3.7)

1A, 1B, 2

Specific target organ toxicity – single exposure (section 3.8)

1, 2

Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity – single exposure; narcotic effects (section 3.8)

3

Specific target organ toxicity – repeated exposure (section 3.9)

1, 2

Aspiration hazard (section 3.10)

1

Hazardous to the aquatic environment – acute aquatic hazard (section 4.1)

1

Hazardous to the aquatic environment – chronic aquatic hazard (section 4.1)

1, 2, 3, 4

▼M12

P502

Refer to manufacturer or supplier for information on recovery or recycling

Hazardous to the ozone layer (Section 5.1)

1

 

▼M19

P503

Refer to manufacturer/ supplier/… for information on disposal/recovery/ recycling

Explosives (section 2.1)

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5

… Manufacturer/supplier to specify appropriate source of information in accordance with local/regional/national/international regulations as applicable.

Code

Disposal precautionary statements

Hazard class

Hazard category

Conditions for use

Code

Code

Disposal precautionary statements

Disposal precautionary statements

Hazard class

Hazard class

Hazard category

Hazard category

Conditions for use

Conditions for use

(1)

(2)

(3)

(4)

(5)

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

(5)

(5)

▼M19

▼M19

▼M19 ▼M19

P501

Dispose of contents/container to …

Flammable liquids (section 2.6)

1, 2, 3

… in accordance with local/regional/national/international regulation (to be specified).

Manufacturer/supplier to specify whether disposal requirements apply to contents, container or both.

P501

P501

Dispose of contents/container to …

Dispose of contents/container to …

Flammable liquids (section 2.6)

Flammable liquids (section 2.6)

1, 2, 3

1, 2, 3

… in accordance with local/regional/national/international regulation (to be specified).

Manufacturer/supplier to specify whether disposal requirements apply to contents, container or both.

… in accordance with local/regional/national/international regulation (to be specified).

Manufacturer/supplier to specify whether disposal requirements apply to contents, container or both.

Self-reactive substances and mixtures (section 2.8)

Types A, B, C, D, E, F

Self-reactive substances and mixtures (section 2.8)

Self-reactive substances and mixtures (section 2.8)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

Substances and mixtures which, in contact with water, emit flammable gases (section 2.12)

1, 2, 3

1, 2, 3

Oxidising liquids (section 2.13)

1, 2, 3

Oxidising liquids (section 2.13)

Oxidising liquids (section 2.13)

1, 2, 3

1, 2, 3

Oxidising solids (section 2.14)

1, 2, 3

Oxidising solids (section 2.14)

Oxidising solids (section 2.14)

1, 2, 3

1, 2, 3

Organic peroxides (section 2.15)

Types A, B, C, D, E, F

Organic peroxides (section 2.15)

Organic peroxides (section 2.15)

Types A, B, C, D, E, F

Types A, B, C, D, E, F

Desensitised explosives (section 2.17)

1, 2, 3, 4

Desensitised explosives (section 2.17)

Desensitised explosives (section 2.17)

1, 2, 3, 4

1, 2, 3, 4

Acute toxicity – oral (section 3.1)

1, 2, 3, 4

Acute toxicity – oral (section 3.1)

Acute toxicity – oral (section 3.1)

1, 2, 3, 4

1, 2, 3, 4

Acute toxicity – dermal (section 3.1)

1, 2, 3, 4

Acute toxicity – dermal (section 3.1)

Acute toxicity – dermal (section 3.1)

1, 2, 3, 4

1, 2, 3, 4

Acute toxicity – inhalation (section 3.1)

1, 2, 3

Acute toxicity – inhalation (section 3.1)

Acute toxicity – inhalation (section 3.1)

1, 2, 3

1, 2, 3

Skin corrosion (section 3.2)

1, 1A, 1B, 1C

Skin corrosion (section 3.2)

Skin corrosion (section 3.2)

1, 1A, 1B, 1C

1, 1A, 1B, 1C

Respiratory sensitisation (section 3.4)

1, 1A, 1B

Respiratory sensitisation (section 3.4)

Respiratory sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

Skin sensitisation (section 3.4)

1, 1A, 1B

Skin sensitisation (section 3.4)

Skin sensitisation (section 3.4)

1, 1A, 1B

1, 1A, 1B

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

Germ cell mutagenicity (section 3.5)

Germ cell mutagenicity (section 3.5)

1A, 1B, 2

1A, 1B, 2

Carcinogenicity (section 3.6)

1A, 1B, 2

Carcinogenicity (section 3.6)

Carcinogenicity (section 3.6)

1A, 1B, 2

1A, 1B, 2

Reproductive toxicity (section 3.7)

1A, 1B, 2

Reproductive toxicity (section 3.7)

Reproductive toxicity (section 3.7)

1A, 1B, 2

1A, 1B, 2

Specific target organ toxicity – single exposure (section 3.8)

1, 2

Specific target organ toxicity – single exposure (section 3.8)

Specific target organ toxicity – single exposure (section 3.8)

1, 2

1, 2

Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8)

3

Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8)

Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8)

3

3

Specific target organ toxicity – single exposure; narcotic effects (section 3.8)

3

Specific target organ toxicity – single exposure; narcotic effects (section 3.8)

Specific target organ toxicity – single exposure; narcotic effects (section 3.8)

3

3

Specific target organ toxicity – repeated exposure (section 3.9)

1, 2

Specific target organ toxicity – repeated exposure (section 3.9)

Specific target organ toxicity – repeated exposure (section 3.9)

1, 2

1, 2

Aspiration hazard (section 3.10)

1

Aspiration hazard (section 3.10)

Aspiration hazard (section 3.10)

1

1

Hazardous to the aquatic environment – acute aquatic hazard (section 4.1)

1

Hazardous to the aquatic environment – acute aquatic hazard (section 4.1)

Hazardous to the aquatic environment – acute aquatic hazard (section 4.1)

1

1

Hazardous to the aquatic environment – chronic aquatic hazard (section 4.1)

1, 2, 3, 4

Hazardous to the aquatic environment – chronic aquatic hazard (section 4.1)

Hazardous to the aquatic environment – chronic aquatic hazard (section 4.1)

1, 2, 3, 4

1, 2, 3, 4

▼M12

▼M12

▼M12 ▼M12

P502

Refer to manufacturer or supplier for information on recovery or recycling

Hazardous to the ozone layer (Section 5.1)

1

 

P502

P502

Refer to manufacturer or supplier for information on recovery or recycling

Refer to manufacturer or supplier for information on recovery or recycling

Hazardous to the ozone layer (Section 5.1)

Hazardous to the ozone layer (Section 5.1)

1

1

 

 

▼M19

▼M19

▼M19 ▼M19

P503

Refer to manufacturer/ supplier/… for information on disposal/recovery/ recycling

Explosives (section 2.1)

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5

… Manufacturer/supplier to specify appropriate source of information in accordance with local/regional/national/international regulations as applicable.

P503

P503

Refer to manufacturer/ supplier/… for information on disposal/recovery/ recycling

Refer to manufacturer/ supplier/… for information on disposal/recovery/ recycling

Explosives (section 2.1)

Explosives (section 2.1)

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5

Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5

… Manufacturer/supplier to specify appropriate source of information in accordance with local/regional/national/international regulations as applicable.

… Manufacturer/supplier to specify appropriate source of information in accordance with local/regional/national/international regulations as applicable.

▼B ▼B