ANNEX V / HAZARD PICTOGRAMS
ANNEX V
HAZARD PICTOGRAMS
INTRODUCTION
The hazard pictograms for each hazard class, differentiation of a hazard class and hazard category shall satisfy the provisions of this Annex and Annex I, section 1.2 and conform in terms of symbols and general format, to the specimens shown.
1. PART 1: PHYSICAL HAZARDS
1.1. Symbol: exploding bomb
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Pictogram (1) |
Hazard class and hazard category (2) |
|
GHS01 |
Section 2.1 Unstable explosives Explosives of Divisions 1.1, 1.2, 1.3, 1.4 Section 2.8 Self reactive substances and mixtures, Types A, B Section 2.15 Organic peroxides, Types A, B |
1.2. Symbol: flame
|
Pictogram (1) |
Hazard class and hazard category (2) |
|
GHS02 |
Section 2.2 ►M19 Flammable gases, hazard categories 1A, 1B. ◄ Section 2.3 ►M4 Aerosols, hazard categories 1, 2 ◄ Section 2.6 Flammable liquids, hazard categories 1, 2, 3 Section 2.7 Flammable solids, hazard categories 1, 2 Section 2.8 Self-reactive substances and mixtures, Types B, C, D, E, F Section 2.9 Pyrophoric liquids, hazard category 1 Section 2.10 Pyrophoric solids, hazard category 1 Section 2.11 Self-heating substances and mixtures, hazard categories 1, 2 Section 2.12 Substances and mixtures, which in contact with water, emit flammable gases, hazard categories 1, 2, 3 Section 2.15 Organic peroxides, Types B, C, D, E, F ►M19 Section 2.17 Desensitised explosives, hazard categories 1, 2, 3, 4 ◄ |
1.3. Symbol: flame over circle
|
Pictogram (1) |
Hazard class and hazard category (2) |
|
GHS03 |
Section 2.4 Oxidising gases, hazard category 1 Section 2.13 Oxidising liquids, hazard categories 1, 2, 3 Section 2.14 Oxidising solids, hazard categories 1, 2, 3 |
1.4. Symbol: gas cylinder
|
Pictogram (1) |
Hazard class and hazard category (2) |
|
GHS04 |
Section 2.5 Gases under pressure: Compressed gases; Liquefied gases; Refrigerated liquefied gases; Dissolved gases |
1.5. Symbol: corrosion
|
Pictogram (1) |
Hazard class and hazard category (2) |
|
GHS05 |
Section 2.16 Corrosive to metals, hazard category 1 |
1.6. A pictogram is not required for the following physical hazard classes and hazard categories:
Section 2.1: Explosives of Division 1.5
Section 2.1: Explosives of Division 1.6
Section 2.2: Flammable gases, hazard Category 2
Section 2.3: Aerosols, hazard Category 3
Section 2.8: Self-reactive substances and mixtures, Type G
Section 2.15: Organic peroxides, Type G
2. PART 2: HEALTH HAZARDS
2.1. Symbol: skull and crossbones
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Pictogram (1) |
Hazard class and hazard category (2) |
|
GHS06 |
Section 3.1 Acute toxicity (oral, dermal, inhalation), hazard categories 1, 2, 3 |
2.2. Symbol: corrosion
|
Pictogram (1) |
Hazard class and hazard category (2) |
|
GHS05 |
Section 3.2 Skin corrosion, hazard category 1 and sub-categories 1A, 1B, 1C Section 3.3 Serious eye damage, hazard category 1 |
2.3. Symbol: exclamation mark
|
Pictogram (1) |
Hazard class and hazard category (2) |
|
►M2
|
Section 3.1 Acute toxicity (oral, dermal, inhalation), hazard category 4 Section 3.2 Skin irritation, hazard category 2 Section 3.3 Eye irritation, hazard category 2 Section 3.4 ►M2 Skin sensitisation, hazard categories 1, 1A, 1B ◄ Section 3.8 Specific Target Organ Toxicity — Single exposure, hazard category 3 Respiratory tract irritation Narcotic effects |
2.4. Symbol: health hazard
|
Pictogram (1) |
Hazard class and hazard category (2) |
|
GHS08 |
Section 3.4 ►M2 Respiratory sensitisation, hazard categories 1, 1A, 1B ◄ Section 3.5 Germ cell mutagenicity, hazard categories 1A, 1B, 2 Section 3.6 Carcinogenicity, hazard categories 1A, 1B, 2 Section 3.7 Reproductive toxicity, hazard categories 1A, 1B, 2 Section 3.8 Specific Target Organ Toxicity — Single exposure, hazard categories 1, 2 Section 3.9 Specific Target Organ Toxicity — Repeated exposure, hazard categories 1, 2 Section 3.10 Aspiration hazard, hazard category 1 |
2.5. A pictogram is not required for the following health hazard categories:
Section 3.7: Reproductive toxicity, Effects on or via lactation, additional hazard category
3. PART 3: ENVIRONMENTAL HAZARDS
3.1. Symbol: environment
|
Pictogram (1) |
Hazard class and hazard category (2) |
|
GHS09 |
Section 4.1 Hazardous to the aquatic environment — Acute hazard category: Acute 1 — Long-term hazard categories: Chronic 1, Chronic 2 |
A pictogram is not required for the following environmental hazard classes and hazard categories:
Section 4.1: Hazardous to the aquatic environment — Long-term hazard categories: Chronic 3, Chronic 4.
4. PART 4: ADDITIONAL HAZARDS
4.1. Symbol: exclamation mark
|
Pictogram |
Hazard class and hazard category |
|
(1) |
(2) |
|
GHS07
|
Section 5.1 Hazardous to the ozone layer, hazard category 1 |